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A highly sensitive multifunctional Eu-MOF sensor with pentacarboxylate for fluorescence detecting acetone, Cu2+ and Cr2O72−, and electrochemical detection of TNP
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2020-01-18 , DOI: 10.1016/j.jssc.2020.121199
Loujun Gao , Chunxia Jiao , Hongmei Chai , Yixia Ren , Gangqiang Zhang , Hao Yu , Long Tang

A novel Eu-MOF sensor, named as [Eu5(DBA)3]n (1), has been prepared based on 3,5-di(2′,4′-dicarboxylphenyl) benozoic acid (H5DBA) and europium nitrate under solvothermal condition. Structural analysis shows that the binuclear and polynuclear inorganic building untis to form stable microporous structure based on the wholly deprotonated DBA ligands. The microporous structure of 1 has been verified by the gas adsorption experiment of N2. Fluorescence studies show that Eu-MOF can detect acetone molecules, Cu2+ ion and Cr2O72− anion with high sensitivity and selectivity, and can also be used for electrochemical detection of exposed 2,4,6-trinitrophenol (TNP) in water. The high selective and sensitive detection ability of complex 1 might make it a potential multifunctional sensor in the future.



中文翻译:

具有五羧酸盐的高灵敏度多功能Eu-MOF传感器,用于荧光检测丙酮,Cu 2+和Cr 2 O 7 2-以及TNP的电化学检测

基于3,5-二(2',4'-二羧基苯基)苯甲酸(H 5 DBA)和euro,制备了一种名为[Eu 5(DBA)3 ] n1)的新型Eu-MOF传感器。溶剂热条件下的硝酸盐。结构分析表明,基于全去质子化的DBA配体,双核和多核无机建筑无法形成稳定的微孔结构。N 2的气体吸附实验已验证了1的微孔结构。荧光研究表明Eu-MOF可以检测丙酮分子,Cu 2+离子和Cr 2 O 7 2-具有高灵敏度和选择性的阴离子,也可用于电化学检测水中暴露的2,4,6-三硝基苯酚(TNP)。配合物1的高选择性和灵敏检测能力可能使其成为未来的潜在多功能传感器。

更新日期:2020-01-21
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