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Honeycomb oxygen-generator with doped bismuth-oxide-based electrolyte and Ag electrode
Journal of Electroceramics ( IF 1.7 ) Pub Date : 2020-01-17 , DOI: 10.1007/s10832-020-00202-x
Sea-Fue Wang , Yu-Wen Chen , Yung-Fu Hsu

This study reports a novel honeycomb oxygen-generator using Y-doped Bi2O3 as the electrolyte and Ag as the electrode. The oxygen generator with a honeycomb-type structure has the dimensions of 40 mm × 35 mm × 30 mm and consists of 13 × 12 channels. The external wire circuitries of the channels arrayed in series-parallel hybrid connections were evaluated to achieve the best efficiency of oxygen evolution, which facilitated the maximum oxygen output of 117 sccm and high purity of >99.9% at 550 °C under a current flow of 14 A. Five Ag electrodes with 5 wt% silane and various amounts of high-temperature glass up to 5 wt% were employed to increase the thermal stability of the modules during operation. The results indicated that the module with an Ag electrode having 3 wt% glass exhibits the best performance with the oxygen output per unit area of 0.87 cm/min at a current density of 0.385 A/cm2 and the lowest decay rate.



中文翻译:

掺杂有氧化铋基电解液和Ag电极的蜂窝式制氧机

这项研究报告了一种新型的使用Y掺杂Bi 2 O 3的蜂窝式氧气发生器作为电解质,Ag作为电极。蜂窝型制氧机的尺寸为40 mm×35 mm×30 mm,由13×12个通道组成。对串联-并联混合连接中排列的通道的外部导线电路进行了评估,以实现最佳的氧气释放效率,在电流为550°C的条件下,在550°C的温度下,其最大氧气输出为117 sccm,高纯度为> 99.9%。 14A。五个具有5wt%硅烷的银电极和高达5wt%的各种量的高温玻璃被用来增加模块在操作期间的热稳定性。结果表明,具有3wt%玻璃的Ag电极的模块表现出最佳性能,在0.385A / cm 2的电流密度下每单位面积的氧气输出为0.87cm / min。 和最低的衰减率。

更新日期:2020-04-21
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