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Cascade reactions to 2,4-disubstituted thiazoles via ligand-free palladium(II)-catalyzed C(sp)–C(sp2) coupling
Tetrahedron ( IF 2.1 ) Pub Date : 2020-01-17 , DOI: 10.1016/j.tet.2020.130953
Zi-Juan Wang , Wen-Teng Chen , Chang He , Hao-Fan Luo , Guo-Lin Zhang , Yong-Ping Yu

A simple construction for various 2,4-disubstituted thiazoles via palladium(II)-catalyzed C(sp)–C(sp2) and C-N cascade coupling reactions was developed. Various substrates can be tolerated with good yields. And its ligand-free condition demonstrates the practicability of this method.



中文翻译:

通过无配体的钯(II)催化的C(sp)–C(sp 2)偶联反应与2,4-二取代的噻唑的级联反应

通过钯(II)催化的C(sp)–C(sp 2)和CN级联偶联反应,开发了各种2,4-二取代噻唑的简单结构。可以耐受各种底物,且产率高。并且其无配体条件证明了该方法的实用性。

更新日期:2020-01-17
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