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Lattice structure and microwave dielectric properties of La[Al1−x(Mg0.5Ti0.5)x]O3 (x = 0‐0.2)‐based ceramics
Journal of the American Ceramic Society ( IF 3.9 ) Pub Date : 2020-01-23 , DOI: 10.1111/jace.17016
Jun Fan 1, 2 , Qing Zhao 1, 2 , Kang Du 1, 2 , Fei Wang 1, 2 , Xiao‐Hong Wang 1, 2 , Wen‐Zhong Lu 1, 2 , Wen Lei 1, 2
Affiliation  

La[Al1−x(Mg0.5Ti0.5)x]O3 (LAMT, x = 0‐0.2) ceramics were synthesized by the conventional solid‐state reaction method and formed a solid solution. The pure solid solutions were recorded by X‐ray diffraction (XRD) in every range. Relative permittivity (εr) and structural stability were greatly affected because the Al3+ site was replaced by [Mg0.5Ti0.5]3+. The total ionic polarizability gradually increased with x, and εr gradually increased. The trend of τf is due to the change in structural stability. The variation in Q × f value increased firstly and then decreased due to the change in the symmetric stretching mode of Al/MgTi–O. The optimum microwave dielectric properties of LAMT were obtained at x of 0.1 after sintering at 1650°C for 5 hours, and εr = 24.9, Q × f = 79 956 GHz, and τf = −33 ppm/°C. The CaTiO3 have a large positive τf (+800 ppm/°C), thus, the τf achieved near zero when CaTiO3 and LAMT (x = 0.1) ceramics were mixed with a certain molar mass, and the optimum microwave dielectric properties of 0.65CaTiO3–0.35LaAl0.9(Mg0.5Ti0.5)0.1O3 were as follows: εr = 44.6, Q × f = 32 057 GHz, and τf = +2 ppm/°C.

中文翻译:

La [Al1-x(Mg0.5Ti0.5)x] O3(x = 0-0.2)基陶瓷的晶格结构和微波介电性能

 通过常规固相反应方法合成了La [Al 1- x(Mg 0.5 Ti 0.5x ] O 3(LAMT,x = 0-0.2)陶瓷,并形成了固溶体。通过X射线衍射(XRD)在每个范围内记录纯固溶体。相对介电常数(ε - [R )和结构稳定性受到很大的影响,因为在Al 3+网站是由[镁代替0.50.5 ] 3+。总离子极化与逐渐增加X,和ε - [R逐渐增加。τ的趋势f是由于结构稳定性的变化。由于Al / MgTi–O对称拉伸模式的变化,Q×f值的变化先增大然后减小。在得到LAMT的最佳微波介电性能X在1650℃下烧结5小时后的0.1,并且ε - [R  = 24.9,Q  ×  ˚F = 79 956千兆赫,和τ ˚F  = -33 PPM /℃。所述的CaTiO 3具有大的正τ ˚F(800 PPM /℃),因此,τ ˚F接近零时的CaTiO实现3和LAMT(X = 0.1)陶瓷用一定的摩尔质量混合,0.65CaTiO的最佳微波介电性能3 -0.35LaAl 0.9(MG 0.5的Ti 0.50.1 ø 3如下:ε - [R  = 44.6,Q  ×  ˚F = 32 057千兆赫,和τ ˚F  = 2 PPM /℃。
更新日期:2020-01-23
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