当前位置: X-MOL 学术Coordin. Chem. Rev. › 论文详情
Highvalent 3d metal-oxo mediated C–H halogenation: Biomimetic approaches
Coordination Chemistry Reviews ( IF 13.476 ) Pub Date : 2020-01-16 , DOI: 10.1016/j.ccr.2019.213174
Jyoti Prasad Biswas; Srimanta Guin; Debabrata Maiti

Enzymes are most efficient catalyst for organic transformations including halogenation of C–H bonds. Most of the halogenating enzymes utilize high valent metal-oxo intermediates for hydrogen atom abstraction (HAA) and subsequent haloalkane formation. Due to high demand of organohalide compounds, many attempts have been made to mimic the active sites of halogenating enzymes in order to achieve efficacy of enzymes. Different first row transition metals complexes have been synthesized using various ligand systems. In this review, we have summarized the efforts made towards development of halogenation using high valent metal-oxo complexes and understanding the mechanism of their activity.
更新日期:2020-01-16

 

全部期刊列表>>
Springer Nature 2019高下载量文章和章节
化学/材料学中国作者研究精选
《科学报告》最新环境科学研究
ACS材料视界
自然科研论文编辑服务
中南大学国家杰青杨华明
南开大学陈弓课题组招聘启事
中南大学
材料化学和生物传感方向博士后招聘
课题组网站
X-MOL
北京大学分子工程苏南研究院
华东师范大学分子机器及功能材料
中山大学化学工程与技术学院
试剂库存
天合科研
down
wechat
bug