This critical review highlighted recent efforts toward the development of the nanoscale synthesis of nonprecious metal's graphene‐supported electrocatalysts and their electrocatalytic features for remarkable hydrogen evolution reaction (HER). Different essential nonprecious metal's graphene‐supported electrocatalysts, including metal carbides, sulfides, phosphides, selenides, oxides, and nitrides are reviewed. In the exploration, attention is given to the strategies of activity enhancement, the synthetic approach, and the composition/structure electrocatalytic‐performance relationship of these HER electrocatalysts. We are hopeful that this review confers a new momentum to the rational design of remarkable performance nonprecious metal's graphene‐supported electrocatalysts and comprehensive guide for researchers to utilize the subject catalysts in regular water splitting.

中文翻译：

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非贵金属的石墨烯负载型电催化剂用于氢气释放反应：应用基础

这篇重要的评论重点介绍了最近为纳米级合成非贵金属的石墨烯负载的电催化剂及其可实现显着氢释放反应（HER）的电催化特性的努力。审查了不同的基本非贵金属的石墨烯负载型电催化剂，包括金属碳化物，硫化物，磷化物，硒化物，氧化物和氮化物。在探索中，关注的是这些HER电催化剂的活性增强策略，合成方法以及组成/结构的电催化性能关系。我们希望这次审查为卓越性能非贵金属的合理设计提供新动力。