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Elaboration of Functionalized Organophosphates.
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2020-01-15 , DOI: 10.1021/acs.joc.9b03324
Kouassi Signo 1 , Zahra Mammasse 1 , Sylvain Canesi 1
Affiliation  

In this study, the rapid transformation of inexpensive phenols into polyfunctionalized cyclohexenones containing a phosphonate in one pot is described. Such systems readily obtained from simple aromatic compounds could open up a multitude of synthetic possibilities. For example, this scaffold was easily and stereoselectively transformed into the corresponding enol functionality in the same pot by the addition of sodium borohydride.

中文翻译:

精制功能化有机磷酸酯。

在这项研究中,描述了一种廉价的酚在一个锅中迅速转变为含有膦酸酯的多官能化环己烯酮的方法。由简单的芳族化合物容易获得的此类体系可以开辟许多合成可能性。例如,通过添加硼氢化钠,可以在同一罐中容易且立体选择性地将该支架转化为相应的烯醇官能度。
更新日期:2020-01-23
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