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Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst.
ACS Omega ( IF 3.7 ) Pub Date : 2020-01-03 , DOI: 10.1021/acsomega.9b02040
Altafhusen G Naikwade 1 , Megha B Jagadale 1 , Dolly P Kale 1 , Anna D Gophane 1 , Kalyanrao M Garadkar 1 , Gajanan S Rashinkar 1
Affiliation  

A magnetically retrievable ferrocene appended supported ionic liquid phase (SILP) photocatalyst containing a molybdate anion has been synthesized and characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectroscopy, and vibrating sample magnetometer analysis. The optical properties of the photocatalyst were probed by photoluminescence and UV-vis diffuse reflectance spectroscopy. The discharge of undesirable dye effluents from textile industrial plants in the environment is the major concern of environmental pollution and toxicity. In this context, we employed the as-prepared SILP photocatalyst for degradation of methyl orange (MO) under UV light (365 nm) irradiation, and subsequently, recycling studies were performed. The histological alteration in gills of the fish is employed as a tool for monitoring toxins in the environment. In view of this, the histo-toxicological assessment on freshwater fish Tilapia mossambica gills asserted the damage of secondary gill lamellae due to MO. Conversely, structural modifications in the gill architecture were not observed by virtue of photodegraded products confirming that the degraded product is nontoxic in nature. Additionally, the normal behavior of fishes on exposure to photodegraded products reveals that research findings are beneficial for the aquatic ecosystem.

中文翻译:


磁性可回收负载型离子液体相光催化剂光催化降解甲基橙。



合成了一种磁性可回收二茂铁附加负载型离子液体相(SILP)光催化剂,并通过傅里叶变换红外、X射线光电子能谱、透射电子显微镜、X射线衍射、能量色散光谱和振动样品磁强计进行了表征和表征。分析。通过光致发光和紫外可见漫反射光谱探讨了光催化剂的光学性质。纺织工厂向环境中排放不良染料废水是环境污染和毒性的主要问题。在此背景下,我们采用所制备的SILP光催化剂在紫外光(365 nm)照射下降解甲基橙(MO),随后进行了回收研究。鱼鳃的组织学变化被用作监测环境中毒素的工具。鉴于此,对淡水鱼莫桑比克罗非鱼鳃的组织毒理学评估表明,MO对次生鳃片造成了损害。相反,光降解产物没有观察到鳃结构的结构改变,这证实了降解产物本质上是无毒的。此外,鱼类接触光降解产品后的正常行为表明,研究结果对水生生态系统有益。
更新日期:2020-01-14
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