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Dramatic morphological reservation of prism-type Cu6Sn5 formed on single crystal Cu substrates under temperature gradient
Materials Today Communications ( IF 3.7 ) Pub Date : 2020-01-14 , DOI: 10.1016/j.mtcomm.2020.100928
Y.Y. Qiao , N. Zhao , C.Y. Liu , C.M.L. Wu , Y.P. Wang , H.T. Ma

The morphology evolution of Cu6Sn5 grains in (001)Cu/Sn/Cu and (011)Cu/Sn/Cu micro solder joints reflowing with and without a temperature gradient was studied. In the as-soldered state, regular and perpendicular prism-type Cu6Sn5 grains formed on (001)Cu substrate, while a mixture of stubby prism-type and scallop-type Cu6Sn5 grains formed on (011)Cu substrate. The prism-type morphology gradually transferred into scallop-type after isothermally reflowed at 270 °C for 10 min. However, with a temperature gradient, the initial perpendicular small prismatic Cu6Sn5 grains on (001)Cu substrate and mixed-type Cu6Sn5 grains on (011)Cu continued to grow into large prism-type. All the prism-type Cu6Sn5 grains grew along same direction after long time reflow under temperature gradient due to the merging of adjacent Cu6Sn5 grain pair.



中文翻译:

在温度梯度下在单晶铜衬底上形成的棱镜型Cu 6 Sn 5的剧烈形态保留

研究了(001)Cu / Sn / Cu和(011)Cu / Sn / Cu微焊点中有无温度梯度回流时Cu 6 Sn 5晶粒的形貌演变。在焊接状态下,在(001)Cu衬底上形成规则和垂直的棱柱形Cu 6 Sn 5晶粒,而在(011)Cu衬底上形成粗短棱柱形和扇贝形Cu 6 Sn 5晶粒的混合物。在270°C等温回流10分钟后,棱柱形形态逐渐转变为扇贝形。但是,在温度梯度的作用下,(001)Cu衬底上的初始垂直小棱形Cu 6 Sn 5晶粒和混合型Cu 6(011)Cu上的Sn 5晶粒继续长成大棱柱形。由于相邻的Cu 6 Sn 5晶粒对的合并,所有的棱柱型Cu 6 Sn 5晶粒在长时间回流后在温度梯度下沿相同方向生长。

更新日期:2020-01-14
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