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A promising cation of 4-aminofurazan-3-carboxylic acid amidrazone in desensitizing energetic materials
RSC Advances ( IF 3.9 ) Pub Date : 2020-1-14 , DOI: 10.1039/c9ra09555a Jichuan Zhang 1, 2 , Zhenyuan Wang 3 , Yunhao Hsieh 3 , Binshen Wang 3 , Haifeng Huang 1 , Jun Yang 1 , Jiaheng Zhang 2, 3
RSC Advances ( IF 3.9 ) Pub Date : 2020-1-14 , DOI: 10.1039/c9ra09555a Jichuan Zhang 1, 2 , Zhenyuan Wang 3 , Yunhao Hsieh 3 , Binshen Wang 3 , Haifeng Huang 1 , Jun Yang 1 , Jiaheng Zhang 2, 3
Affiliation
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For the development of energetic materials, insensitive compounds have attracted considerable attention due to their improved safety and lower cost than those of sensitive energetic compounds during production, transportation, and application. In this study, insensitive 4-aminofurazan-3-carboxylic acid amidrazone was used as a cation to obtain four derivatives which were determined by X-ray single crystal diffraction. It is interesting to note that all four derivatives are insensitive to impact and friction, while the velocities of detonation for derivatives are superior to that of insensitive TATB (1,3,5-triamino-2,4,6-trinitrobenzene). Multi-factors analysis shows that the cation of 4-aminofurazan-3-carboxylic acid amidrazone is a promising furazan-based cation in desensitizing energetic compounds.
中文翻译：
4-氨基呋喃-3-羧酸氨基腙阳离子在含能材料脱敏中的应用前景
在含能材料的开发中，不敏感化合物由于其在生产、运输和应用过程中比敏感含能化合物具有更高的安全性和更低的成本而引起了人们的广泛关注。本研究以不敏感的4-氨基呋喃-3-羧酸脒腙为阳离子，得到4种衍生物，经X射线单晶衍射测定。有趣的是，所有四种衍生物都对冲击和摩擦不敏感，而衍生物的爆轰速度优于不敏感的 TATB（1,3,5-三氨基-2,4,6-三硝基苯）。多因素分析表明，4-氨基呋喃-3-羧酸氨基腙阳离子是一种很有前景的呋喃阳离子，可用于含能化合物的脱敏。
更新日期：2020-01-14
中文翻译：
4-氨基呋喃-3-羧酸氨基腙阳离子在含能材料脱敏中的应用前景
在含能材料的开发中，不敏感化合物由于其在生产、运输和应用过程中比敏感含能化合物具有更高的安全性和更低的成本而引起了人们的广泛关注。本研究以不敏感的4-氨基呋喃-3-羧酸脒腙为阳离子，得到4种衍生物，经X射线单晶衍射测定。有趣的是，所有四种衍生物都对冲击和摩擦不敏感，而衍生物的爆轰速度优于不敏感的 TATB（1,3,5-三氨基-2,4,6-三硝基苯）。多因素分析表明，4-氨基呋喃-3-羧酸氨基腙阳离子是一种很有前景的呋喃阳离子，可用于含能化合物的脱敏。
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