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Acylation and Palladium-Mediated Couplings of Maltol, a Biobased γ-Pyrone
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-01-13 , DOI: 10.1016/j.tetlet.2019.151591 Yang Qu , Aleksei V. Ananin , George A. Kraus
中文翻译:
麦芽酚(一种基于生物的γ-吡喃酮)的酰化和钯介导的偶联
更新日期:2020-01-14
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-01-13 , DOI: 10.1016/j.tetlet.2019.151591 Yang Qu , Aleksei V. Ananin , George A. Kraus
Maltol triflate 3 undergoes palladium-mediated carbon-carbon bond formation with styrene, boronic acids and alkynes. Benzyl ether 2 can be acylated. The acylation products can be readily converted into furo[3,2-b]pyranones.
中文翻译:
麦芽酚(一种基于生物的γ-吡喃酮)的酰化和钯介导的偶联
麦芽三氟甲磺酸酯3与苯乙烯,硼酸和炔烃进行钯介导的碳-碳键形成。苄基醚2可以被酰化。酰化产物可以容易地转化为呋喃[3,2-b]吡喃酮。