当前位置：
X-MOL 学术
›
Cryst. Growth Des.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Construction of a Succinate-Bridged Cd(II)-Based Two-Dimensional Coordination Polymer for Efficient Optoelectronic Device Fabrication and Explosive Sensing Application
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2020-01-23 , DOI: 10.1021/acs.cgd.9b01181 Basudeb Dutta 1 , Abhijit Hazra 2, 3 , Arka Dey 4, 5 , Chittaranjan Sinha 6 , Partha Pratim Ray 4 , Priyabrata Banerjee 2, 3 , Mohammad Hedayetullah Mir 1
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2020-01-23 , DOI: 10.1021/acs.cgd.9b01181 Basudeb Dutta 1 , Abhijit Hazra 2, 3 , Arka Dey 4, 5 , Chittaranjan Sinha 6 , Partha Pratim Ray 4 , Priyabrata Banerjee 2, 3 , Mohammad Hedayetullah Mir 1
Affiliation
|
A newly designed multifunctional two-dimensional coordination polymer (2D CP) {[Cd(suc)(4-nvp)2]·2H2O}n, (1), (H2suc = succinic acid and 4-nvp = 4-(1-naphthylvinyl)pyridine) has been synthesized and characterized by X-ray crystallography. The solid-state structure of the compound 1 reveals the formation of three-dimensional supramolecular architecture via C–H···π and π···π stacking interactions. Interestingly, the supramolecular assembly of compound 1 exhibits electrical conductivity in the semiconducting nature. A deep insight into the electrical study of compound 1 carried out by dielectric characterization reveals the enhancement of conductivity upon light soaking. Thus, the compound has potential applicability in the fabrication optoelectronic devices. On the other hand, compound 1 shows sensing activity toward explosive nitroaromatic compounds (epNACs), which threatens devastating terror attacks ultimately responsible for massive loss of life. Besides, the nitroaromatic compound (NAC) 2,4,6-trinitrophenol (TNP) can enter inside the mammalian digestive cycle, wherein it gets metabolized into a mutagenic species, picramic acid, which causes health hazards. Compound 1 can detect TNP with the most acceptable fluorescence method. Together with its optoelectronic device fabrication and explosive sensing application, the synthesized material can be used as a potential candidate for sustainability.
中文翻译：
琥珀酸酯桥联Cd（II）的二维配位聚合物的构建，用于高效光电器件的制造和爆炸传感应用
一种新设计的多功能二维配位聚合物（2D CP）{[Cd（suc）（4-nvp）2 ]·2H 2 O} n，（1），（H 2 suc =琥珀酸和4-nvp = 4 -（1-萘基乙烯基）吡啶）已经合成并通过X射线晶体学表征。化合物1的固态结构通过C–H···π和π···π堆积相互作用揭示了三维超分子结构的形成。有趣的是，化合物1的超分子组装体具有半导体性质的导电性。对化合物1的电学研究的深刻见解通过介电特性进行的分析揭示了光浸泡后电导率的增强。因此，该化合物在制造光电器件中具有潜在的适用性。另一方面，化合物1显示出对爆炸性硝基芳香化合物（epNAC）的感应活性，该威胁会威胁毁灭性的恐怖袭击，最终造成重大人员伤亡。此外，硝基芳香族化合物（NAC）2,4,6-三硝基苯酚（TNP）可以进入哺乳动物的消化周期，并被代谢成致突变物种，即苦味酸，对健康造成危害。化合物1可以用最可接受的荧光方法检测TNP。连同其光电器件制造和爆炸物传感应用，合成材料可以用作可持续性的潜在候选者。
更新日期：2020-01-23
中文翻译：
琥珀酸酯桥联Cd（II）的二维配位聚合物的构建，用于高效光电器件的制造和爆炸传感应用
一种新设计的多功能二维配位聚合物（2D CP）{[Cd（suc）（4-nvp）2 ]·2H 2 O} n，（1），（H 2 suc =琥珀酸和4-nvp = 4 -（1-萘基乙烯基）吡啶）已经合成并通过X射线晶体学表征。化合物1的固态结构通过C–H···π和π···π堆积相互作用揭示了三维超分子结构的形成。有趣的是，化合物1的超分子组装体具有半导体性质的导电性。对化合物1的电学研究的深刻见解通过介电特性进行的分析揭示了光浸泡后电导率的增强。因此，该化合物在制造光电器件中具有潜在的适用性。另一方面，化合物1显示出对爆炸性硝基芳香化合物（epNAC）的感应活性，该威胁会威胁毁灭性的恐怖袭击，最终造成重大人员伤亡。此外，硝基芳香族化合物（NAC）2,4,6-三硝基苯酚（TNP）可以进入哺乳动物的消化周期，并被代谢成致突变物种，即苦味酸，对健康造成危害。化合物1可以用最可接受的荧光方法检测TNP。连同其光电器件制造和爆炸物传感应用，合成材料可以用作可持续性的潜在候选者。
京公网安备 11010802027423号