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Synthesis of new polyaryl-substituted imidazoles bridged on enamine or urea moieties and evaluation of their optical and electrochemical properties
Research on Chemical Intermediates ( IF 2.8 ) Pub Date : 2020-01-11 , DOI: 10.1007/s11164-020-04078-y
Ameneh Abolghassemi Fakhree , Roghayeh Mohammadzadeh , Esmaeel Alipour , Zarrin Ghasemi

Abstract

The reaction of the free amine group in polyaryl-substituted imidazole structures with phenyl isocyanate or dimethyl acetylenedicarboxylate gave two new series of polyaryl-substituted imidazoles: biaryl ureas or vinyl esters, respectively. Besides their spectroscopic analysis, we explored the optical and electrochemical properties of these highly conjugated scaffolds. Comparing these properties in two categories of products yielded interesting results.

Graphic abstract



中文翻译:

烯胺或脲部分连接的新型聚芳基取代的咪唑的合成及其光学和电化学性能的评估

摘要

聚芳基取代的咪唑结构中的游离胺基与异氰酸苯基酯或乙酰二羧酸二甲酯的反应得到了两个新的聚芳基取代的咪唑系列:联芳基脲或乙烯基酯。除了其光谱分析之外,我们还探索了这些高度共轭的支架的光学和电化学性质。在两类产品中比较这些性能产生了有趣的结果。

图形摘要

更新日期:2020-01-11
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