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Hybrid adsorption–photocatalysis properties of quaternary magneto-plasmonic ZnO/MWCNTs nanocomposite for applying synergistic photocatalytic removal and membrane filtration in industrial wastewater treatment
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2020-01-10 , DOI: 10.1016/j.jphotochem.2020.112359
Elnaz Irani , Mitra Amoli-Diva

A new multifunctional filtration membrane was prepared by twofold advantages of conventional polymeric-membrane as the supporting layer and magneto-plasmonic Ag-doped [email protected]3O4/MWCNTs nanocomposite as the functional layer. Poly acrylic acid (PAA)-modified polyamide (PA) discs (PAA-PA) were applied to increase the hydrophilicity of prepared membrane and X-Ray diffraction (XRD) and scanning electron microscopy (SEM) techniques were used for characterization. The grafting yield of PAA in the pores and on the surface of PA was 17 wt.% and weigh difference between PAA-PA membrane before and after modifying with the photocatalyst was 8.7 mg. The amount of photocatalyst loading in the prepared membrane was obtained 6.49 g m−2. The synergistic effect of photocatalysis and membrane filtration was evaluated by investigating removal efficiency of amoxicillin (AMOX) as model pollutant using photocatalytic filtration concentration (CPF) parameter under a solar-simulated xenon lamp and the prepared photocatalyst-grafted PAA-PA membrane (PC-PAA-PA) was exhibited better removal ability than bare PA. The flux performance and antifouling property of the prepared membrane was investigated using pharmaceutical wastewater samples and the results revealed that the PC-PAA-PA exhibited good multifunctional characteristics such as high photocatalytic property, flux stability, and antifouling potential. The fouling process was performed in triplicate and the results demonstrated good stability of the photocatalyst on the membrane surface during operation. It can be concluded that by using a simple process for grafting of the photocatalyst to the membrane and the excellent antifouling ability of the resulting filter, an efficient reactor with antifouling characteristics can be constructed to produce cleaner water.



中文翻译:

季磁-等离子体ZnO / MWCNTs纳米复合材料的混合吸附-光催化特性用于协同光催化去除和膜过滤在工业废水处理中的应用

利用传统的高分子膜作为支撑层,并结合了磁等离子体Ag掺杂的[受电子邮件保护的] 3 O 4 / MWCNTs纳米复合膜作为功能层,制备了一种新型的多功能过滤膜。应用聚丙烯酸(PAA)改性的聚酰胺(PA)圆盘(PAA-PA)来增加所制备膜的亲水性,并使用X射线衍射(XRD)和扫描电子显微镜(SEM)技术进行表征。在孔中和在PA表面上的PAA的接枝产率为17重量%,并且用光催化剂改性前后的PAA-PA膜之间的重量差为8.7mg。获得的膜中光催化剂的负载量为6.49 gm -2。通过研究使用光催化过滤浓度(C PF)的阿莫西林(AMOX)作为模型污染物的去除效率来评估光催化和膜过滤的协同效应在太阳光模拟氙灯下的参数)和制备的光催化剂接枝PAA-PA膜(PC-PAA-PA)表现出比裸露PA更好的去除能力。使用制药废水样品对制备的膜的通量性能和防污性能进行了研究,结果表明PC-PAA-PA具有良好的多功能特性,如高光催化性能,通量稳定性和防污潜力。结垢过程进行三次,结果表明在操作过程中光催化剂在膜表面上的良好稳定性。可以得出结论,通过使用一种简单的将光催化剂接枝到膜上的方法以及所得滤纸的优异防污能力,

更新日期:2020-01-10
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