Reduced graphene oxide modified black phosphorus quantum dots ([email protected]) were obtained through surface modification of BPQDs with rGO via an ultrasound-assisted liquid phase method. The [email protected] could effectively enhance the chemical and structural stability of BPQDs. Zero-dimension [email protected] were firmly anchored on mesoporous g-C₃N₄ (CN) via a self-trapping pore confinement effect and π-π interactions to form CN/[email protected], which remarkably improved the photoelectric properties of CN. The responsive wavelength of CN/[email protected] could be extended to 800 nm. The kinetic constant of Rhodamine B and tetracycline degradation reached 0.183 and 0.0194 min⁻¹, respectively. The H₂O₂ production rate of CN/[email protected] was 2.6 times that of porous CN. The improved photocatalytic performance and remarkable increase in free radicals are attributed to the formation of n-n type high-low junctions as well as the internal electric field based on different Fermi levels between CN and BPQDs. These collectively promote spatial separation of photogenerated carriers.

通过超声辅助液相法用rGO对BPQD进行表面修饰，获得了还原的氧化石墨烯修饰的黑磷量子点（[受电子邮件保护]）。受保护的电子邮件可以有效增强BPQD的化学和结构稳定性。零维（受电子邮件保护）通过自陷孔限制作用和π-π相互作用牢固地锚定在介孔gC ₃ N ₄（CN）上，形成CN / [受电子邮件保护]，从而显着提高了CN的光电性能。CN / [受电子邮件保护]的响应波长可以扩展到800 nm。若丹明B和四环素降解的动力学常数分别达到0.183和0.0194 min ^-1。H ₂ O ₂CN / [受电子邮件保护]的生产率是多孔CN的2.6倍。改进的光催化性能和自由基的显着增加归因于nn型高低结的形成以及基于CN和BPQD之间不同费米能级的内部电场。这些共同促进了光生载流子的空间分离。