A detailed analysis of recent advances in the use of metal-containing monomers as precursors for the preparation of core–shell nanostructured advanced materials by the method of conjugated thermolysis was carried out. This method consists in the simultaneous course of the processes of thermal polymerization of monomers and the formation of metal-containing nanoparticles during thermal transformation. The general scheme of conjugated thermolysis includes three successive stages: dehydration (desolvation), polymerization and thermolysis of the resulting metallopolymers. Particular attention was paid to the composition of solid-phase products of conjugated thermolysis. Kinetic schemes and reactions of thermal transformation of metal-containing monomers were analyzed. The use of the obtained nanocomposites as magnetic materials, sensors, catalysts and tribological materials was generalized. Problems and prospects of using conjugated thermolysis for the production of advanced nanomaterials were outlined.

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含金属单体的共轭热解：向核-壳纳米结构的先进材料发展

对通过共轭热解法制备含金属单体作为前体用于制备核-壳纳米结构先进材料的最新进展进行了详细分析。该方法在于单体的热聚合和在热转化过程中形成含金属的纳米颗粒的过程同时进行。共轭热解的一般方案包括三个连续的阶段：脱水（脱溶剂），聚合和所得金属聚合物的热解。特别关注共轭热解的固相产物的组成。分析了含金属单体的热转化动力学方案和反应。将获得的纳米复合材料用作磁性材料，传感器，归纳了催化剂和摩擦学材料。概述了使用共轭热解技术生产高级纳米材料的问题和前景。