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Evaluation of the inhibition behavior of carbon dots on carbon steel in HCl and NaCl solutions
Journal of Materials Science & Technology ( IF 11.2 ) Pub Date : 2020-01-08 , DOI: 10.1016/j.jmst.2020.01.025
Yuwei Ye , Zilong Jiang , Yangjun Zou , Hao Chen , Shengda Guo , Qiumin Yang , Liyong Chen

An eco-friendly and effective corrosion inhibitor (N-CDs) was acquired by hydrothermal method in methacrylic acid and ethyl(methyl)amine precursors. Afterwards, the weight loss and electrochemistry measurement were chosen to appraise the corrosion inhibition behavior of as-prepared N-CDs for Q235 steel in Cl contained solutions. The change rules of EIS and Tafel data displayed that the as-prepared N-CDs revealed a high-efficiency protection for steel in all test environments. Meanwhile, the inhibition efficiency of steel reached up to 93.93 % (1 M HCl) and 88.96 % (3.5 wt% NaCl) at 200 mg/L of N-CDs. Furthermore, the N-CDs could form the adsorption film on steel surface to avoid the strong attack of Cl. By analysis, the adsorption mechanism of as-prepared N-CDs on steel surface was physicochemical interaction, which strictly complied with the Langmuir adsorption model in both solutions.



中文翻译:

评价碳点在HCl和NaCl溶液中对碳钢的抑制行为

通过水热法在甲基丙烯酸和乙基(甲基)胺前体中获得了一种生态友好,有效的缓蚀剂(N-CDs)。然后,将重量损失和电化学测量被选择用来鉴定为Q235钢在含Cl如此制备的N- CD的缓蚀行为-包含的解决方案。EIS和Tafel数据的变化规则表明,所制备的N-CD在所有测试环境中均显示出对钢的高效保护。同时,在200 mg / L的N-CDs下,钢的抑制效率高达93.93%(1 M HCl)和88.96%(3.5 wt%NaCl)。此外,N型光盘可以形成于钢材表面的吸附膜,以避免Cl组成的攻强-。通过分析,所制备的N-CDs在钢表面的吸附机理为物理化学相互作用,在两种溶液中均严格符合Langmuir吸附模型。

更新日期:2020-01-08
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