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Nickel-Catalyzed Asymmetric Hydrocyanation of Allenes.
Organic Letters ( IF 4.9 ) Pub Date : 2020-01-08 , DOI: 10.1021/acs.orglett.9b03938 Jinguo Long 1 , Jihui Gao 1 , Xianjie Fang 1
Organic Letters ( IF 4.9 ) Pub Date : 2020-01-08 , DOI: 10.1021/acs.orglett.9b03938 Jinguo Long 1 , Jihui Gao 1 , Xianjie Fang 1
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The first catalytic enantioselective hydrocyanation of allenes catalyzed by a (R,R)-Ph-BPE-Ni(0) complex catalyst has been accomplished. Numerous optically active allylic nitriles were obtained in good yield with excellent enantioselectivities (up to 98% ee).
中文翻译:
镍催化的异戊烯不对称氢氰化。
由(R,R)-Ph-BPE-Ni(0)络合物催化剂催化的丙二烯的第一催化对映选择性氢氰化反应已经完成。以良好的收率和优异的对映选择性(高达98%ee)获得了许多旋光性烯丙基腈。
更新日期:2020-01-08
中文翻译:
镍催化的异戊烯不对称氢氰化。
由(R,R)-Ph-BPE-Ni(0)络合物催化剂催化的丙二烯的第一催化对映选择性氢氰化反应已经完成。以良好的收率和优异的对映选择性(高达98%ee)获得了许多旋光性烯丙基腈。