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Improved sub-ppm acetone sensing properties of SnO2 nanowire-based sensor by attachment of Co3O4 nanoparticles
Journal of Materials Research and Technology ( IF 6.2 ) Pub Date : 2020-01-08 , DOI: 10.1016/j.jmrt.2019.12.094
Hongseok Kim , Zhicheng Cai , Sung-Pil Chang , Sunghoon Park

Co3O4 nanoparticle-attached SnO2 nanowires are synthesized to fabricate highly sensitive acetone gas sensor by vapor-liquid-solid (VLS), sol-gel, and thermal annealing processes. To analyze enhanced acetone gas sensing responses, Co3O4 nanoparticles are attached SnO2 nanowires, and several samples are synthesized followed by the cycles of Co3O4 nanoparticle attachment process. The sensing response of Co3O4 nanoparticle-attached SnO2 nanowires, which are one time performed Co3O4 nanoparticle attachment process, is improved by 7 times compared with as-synthesized SnO2 nanowires when exposed to 50 ppm acetone gas. In particular, when exposed to 0.5 ppm acetone gas, as-synthesized SnO2 nanowires present an extremely low response — close to negligible. However, when Co3O4 nanoparticles are attached, the response is improved drastically. Furthermore, the sensing selectivity toward acetone gas is improved compared with its counterpart. This improved sensing property is derived from the increasing variation in the surface depletion area located in the p-n heterojunction.



中文翻译:

通过附着Co 3 O 4纳米颗粒改善SnO 2纳米线基传感器的亚ppm级丙酮感测性能

通过汽-液-固(VLS),溶胶-凝胶和热退火工艺,合成了附着有Co 3 O 4纳米粒子的SnO 2纳米线,以制造高灵敏度的丙酮气体传感器。为了分析增强的丙酮气体感测响应,将Co 3 O 4纳米粒子附着到SnO 2纳米线上,并合成几个样品,然后循环进行Co 3 O 4纳米粒子附着过程。一次执行Co 3 O 4的附着Co 3 O 4纳米粒子的SnO 2纳米线的感测响应当暴露在50 ppm的丙酮气体中时,纳米粒子的附着过程比合成后的SnO 2纳米线提高了7倍。特别是,当暴露于0.5 ppm的丙酮气体中时,合成后的SnO 2纳米线表现出极低的响应-几乎可以忽略不计。然而,当附着Co 3 O 4纳米颗粒时,响应大大改善。此外,与丙酮气体相比,对丙酮气体的感测选择性得到了改善。这种改善的感测特性源自位于pn异质结中的表面耗尽区的变化增加。

更新日期:2020-01-08
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