Pressure-sensitive adhesives (PSAs) are characterized by instantaneous adhesion upon application of light pressure. PSA performance is defined by peel strength, tack and shear strength. The adhesion and cohesion mechanisms are well defined as peel adhesion, loop tack and shear strength in the state of the art and can be adjusted according to the specific requirements. 2-Ethylhexyl acrylate-based latexes have been synthesized with the incorporation of boron methacrylate (BoMA) via mini-emulsion polymerization, and latexes with high surface area were obtained enabling interactive relation with polar and nonpolar surfaces. Cetyl alcohol was used as a cosurfactant to have colloidally stable hydrophobic particles in mini-emulsion polymerization. The incorporation of BoMA at 2% and 4% into the latexes led to an increase in peel adhesion strength on polar and nonpolar substrates. The addition of BoMA decreased the shear strength on both polar and nonpolar substrates at initial and after aging conditions. The shear strength was higher after the polymer films were aged providing a stable and stiff material. The amount of BoMA incisively affects the type of PSA and should be taken into consideration while constructing a polymer for a pre-specified application. The thermal properties were also improved by the addition of BoMA in terms of thermal stability and char yield. The assumptions in question were strongly correlated with peel, shear, loop tack values and thermal analysis.

中文翻译：

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甲基丙烯酸硼单体对微乳液聚合法合成的 2-EHA 共聚物胶乳热压敏粘合性能的影响

压敏粘合剂 (PSA) 的特点是在施加轻微压力时具有瞬时粘合力。PSA 性能由剥离强度、粘性和剪切强度定义。粘合和内聚机制在现有技术中被很好地定义为剥离粘合力、环粘性和剪切强度，并且可以根据具体要求进行调整。通过微乳液聚合引入甲基丙烯酸硼 (BoMA) 合成了基于 2-乙基己基丙烯酸酯的乳胶，并获得了具有高表面积的乳胶，能够与极性和非极性表面相互作用。鲸蜡醇用作辅助表面活性剂以在微乳液聚合中具有胶体稳定的疏水颗粒。在胶乳中加入 2% 和 4% 的 BoMA 导致极性和非极性基材上的剥离粘合强度增加。BoMA 的加入降低了极性和非极性基材在初始和老化条件下的剪切强度。聚合物薄膜老化后剪切强度更高，提供稳定和坚硬的材料。BoMA 的量会深刻影响 PSA 的类型，在构建用于预先指定应用的聚合物时应予以考虑。在热稳定性和焦炭产率方面，添加 BoMA 也改善了热性能。所讨论的假设与剥离、剪切、环粘性值和热分析密切相关。BoMA 的加入降低了极性和非极性基材在初始和老化条件下的剪切强度。聚合物薄膜老化后剪切强度更高，提供稳定和坚硬的材料。BoMA 的量会深刻影响 PSA 的类型，在构建用于预先指定应用的聚合物时应予以考虑。在热稳定性和焦炭产率方面，添加 BoMA 也改善了热性能。所讨论的假设与剥离、剪切、环粘性值和热分析密切相关。BoMA 的加入降低了极性和非极性基材在初始和老化条件下的剪切强度。聚合物薄膜老化后剪切强度更高，提供稳定和坚硬的材料。BoMA 的量会深刻影响 PSA 的类型，在构建用于预先指定应用的聚合物时应予以考虑。在热稳定性和焦炭产率方面，添加 BoMA 也改善了热性能。所讨论的假设与剥离、剪切、环粘性值和热分析密切相关。BoMA 的量会深刻影响 PSA 的类型，在构建用于预先指定应用的聚合物时应予以考虑。在热稳定性和焦炭产率方面，添加 BoMA 也改善了热性能。所讨论的假设与剥离、剪切、环粘性值和热分析密切相关。BoMA 的量会深刻影响 PSA 的类型，在构建用于预先指定应用的聚合物时应予以考虑。在热稳定性和焦炭产率方面，添加 BoMA 也改善了热性能。所讨论的假设与剥离、剪切、环粘性值和热分析密切相关。