Dynamic Ion Correlations in Solid and Liquid Electrolytes: How Do They Affect Charge and Mass Transport?,ChemElectroChem

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Dynamic Ion Correlations in Solid and Liquid Electrolytes: How Do They Affect Charge and Mass Transport?
ChemElectroChem ( IF 3.5 ) Pub Date : 2020-01-08 , DOI: 10.1002/celc.201902042
N. M. Vargas‐Barbosa ₁ , B. Roling ₁

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The Cover Feature illustrates the types of ion correlations that are found in solid and liquid electrolytes used in lithium‐based batteries. The effect of such correlations on the overall mass and change transport, e.g. the salt diffusion coefficient and the transference number of lithium, can be described by combining linear response theory and Onsager′s linear irreversible thermodynamics. In this Review, the theoretical foundation for ionic correlations in solid and liquid electrolytes is presented and applied to recent literature reports.More information can be found in the Review by N. M. Vargas‐Barbosa and B. Roling.

中文翻译：

固体和液体电解质中的动态离子相关性：它们如何影响电荷和质量传输？

封面功能说明了锂基电池使用的固体和液体电解质中发现的离子相关类型。通过将线性响应理论和Onsager的线性不可逆热力学相结合，可以描述这种相关性对整体质量和变化输运的影响，例如盐的扩散系数和锂的转移数。在本综述中，介绍了固体和液体电解质中离子相关性的理论基础并将其应用于最近的文献报道中。更多信息可以在N.M.Vargas-Barbosa和B.Roling的《综述》中找到。

更新日期：2020-01-08

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