Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles.,Chemical Communications

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Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-01-13 , DOI: 10.1039/c9cc09369a
Sensheng Liu ₁ , Martin Klussmann

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A difunctionalization of alkenes through sequential addition of a radical and a nucleophile has been developed, which is suggested to proceed by a radical chain mechanism not requiring a catalyst. An electron transfer step to the oxidant benzoyl peroxide is facilitated by protonation with a strong acid.

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