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Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-01-13 , DOI: 10.1039/c9cc09369a Sensheng Liu 1 , Martin Klussmann
Chemical Communications ( IF 4.3 ) Pub Date : 2020-01-13 , DOI: 10.1039/c9cc09369a Sensheng Liu 1 , Martin Klussmann
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A difunctionalization of alkenes through sequential addition of a radical and a nucleophile has been developed, which is suggested to proceed by a radical chain mechanism not requiring a catalyst. An electron transfer step to the oxidant benzoyl peroxide is facilitated by protonation with a strong acid.
中文翻译:
酸通过稳定的自由基和(N,O)-亲核试剂促进苯乙烯的自由基链双官能化。
已经开发出通过依次添加自由基和亲核试剂来进行烯烃的双官能化,这被建议通过不需要催化剂的自由基链机理进行。用强酸质子化促进了向氧化剂过氧化苯甲酰的电子转移步骤。
更新日期:2020-01-13
中文翻译:
酸通过稳定的自由基和(N,O)-亲核试剂促进苯乙烯的自由基链双官能化。
已经开发出通过依次添加自由基和亲核试剂来进行烯烃的双官能化,这被建议通过不需要催化剂的自由基链机理进行。用强酸质子化促进了向氧化剂过氧化苯甲酰的电子转移步骤。