Gold‐Catalyzed Intermolecular Oxidative Diyne Cyclizations via 1,6‐Carbene Transfer,Advanced Synthesis & Catalysis

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Gold‐Catalyzed Intermolecular Oxidative Diyne Cyclizations via 1,6‐Carbene Transfer
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-01-07 , DOI: 10.1002/adsc.201901610
Qian Wang ₁ , Matthias Rudolph ₁ , Frank Rominger ₁ , A. Stephen K. Hashmi _{1,

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Affiliation

The front cover picture, designed by Qian Wang (from the group of A. S. K. Hashmi) and painted by the artist Yiyun Hu (born in Chang Sha, Hu Nan Province, People′s Republic of China) illustrates gold‐catalyzed intermolecular oxidative diyne cyclizations via 1,6‐carbene transfer. Our method features a 1,6‐carbene shift: an α‐oxo carbene can transfer across a second alkyne. This picture depicts the reagents put into a “gold” traditional Chinese hot pot to give the products. Further details of this work can be found in the communication on pages XXX–XXX (Q. Wang, M. Rudolph, F. Rominger, A. S. K. Hashmi, Adv. Synth. Catal. 2020, 362, XXX–XXX; DOI: 10.1002/adsc.201901318).

更新日期：2020-01-07

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