Gold nanorods (Au NRs) decorated TiO₂(B) nanofibers have been fabricated by electrostatic interaction-annealing approach. The plasmonic Au NRs/TiO₂(B) exhibits high visible-near IR light activity for coupling of amines to imines by air as oxidant in solvent-free conditions. Imines selectivity is switched from ∼50% in the dark to ∼80% under light irradiation and oximes selectivity is decreased from ∼49% in the dark to ∼19% under light irradiation. In the coupling of benzylamine to N-benzylidene benzylamine, the TOF (based on Au content) is up to 111.4∼149.5 h^-1 for Au NRs/TiO₂(B), while the TOF (based on Au surface area) is 3.7 and 4.1 times supported Au nanoparticle counterpart illuminating with visible light and visible-near IR light respectively.

金纳米棒（Au NRs）装饰的TiO ₂（B）纳米纤维已经通过静电相互作用退火方法制备。等离子Au NRs / TiO ₂（B）在无溶剂条件下通过空气作为氧化剂将胺与亚胺偶联时，具有很高的可见光-近红外光活性。在光照射下，亚胺的选择性从暗处的约50％切换到约80％，肟在光照射下的选择性从暗处的约49％降低到约19％。在苄胺与N-亚苄基苄胺的偶合中，Au NRs / TiO ₂的TOF（基于Au含量）高达111.4〜149.5 h ^-1（B），而TOF（基于Au表面积）是分别用可见光和近红外IR照明的支持的Au纳米粒子对应物的3.7和4.1倍。