The dramatic increase in atmospheric carbon dioxide (CO2) concentrations has attracted human attention and many strategies about converting CO2 into high-value chemicals have been put forward. Metal-organic frameworks (MOFs), as a class of versatile materials, have been widely used in CO2 capture and chemical conversion, due to their unique porosity, multiple active centers and good stability and recyclability. Herein, we focused on the processes of chemical conversion of CO2 by MOFs-based catalysts, including the coupling reactions of epoxides, aziridines or alkyne molecules, CO2 hydrogenation, and other CO2 conversion reactions. The synthesized methods and high catalytic activity of MOFs-based materials were also analyzed systematically. Finally, a brief perspective on feasible strategies is presented to improve the catalytic activity of novel MOFs-based materials and explore the new CO2 conversion reactions.

中文翻译：

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基于MOF的催化剂支持CO2的化学转化。

大气中二氧化碳（CO2）浓度的急剧增加引起了人们的关注，并提出了许多将CO2转化为高价值化学品的策略。金属有机骨架（MOF）作为一类通用材料，由于其独特的孔隙率，多个活性中心以及良好的稳定性和可回收性，已被广泛用于CO2捕集和化学转化。在这里，我们集中于基于MOF的催化剂对CO2的化学转化过程，包括环氧化物，氮丙啶或炔烃分子的偶联反应，CO2加氢以及其他CO2转化反应。还对MOFs基材料的合成方法和高催化活性进行了系统的分析。最后，