当前位置: X-MOL 学术J. Solut. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Experimental Determination and Correlation of Liquid–Liquid Equilibria Data for the Ternary Systems of Water + 1-Butanol + Solvents (Isophorone and Mesityl Oxide) at Different Temperatures
Journal of Solution Chemistry ( IF 1.4 ) Pub Date : 2020-01-01 , DOI: 10.1007/s10953-019-00939-2
Yingmin Yu , Lili Zhang , Chuanfu Zhu , Xin Huang , Zhaohui Liao , Qingsong Li

Liquid–liquid equilibria (LLE) data for {water + 1-butanol + isophorone} and {water + 1-butanol + mesityl oxide} ternary systems were investigated systematically at different temperatures under atmospheric pressure. The Othmer–Tobias and Bachman equations were applied to analyze the dependability of the experimental LLE data. Selectivities and distribution coefficients were used to evaluate the extractive efficiency of the extractants. The Non-Random Two Liquid (NRTL) and Universal Quasi-Chemical (UNIQUAC) models were applied to correlate the studied systems and were well represented with all root mean square deviations (RMSD) less than 0.2%. Meanwhile, binary interaction parameters among these compounds were acquired during the correlation process.

中文翻译:

不同温度下水 + 1-丁醇 + 溶剂(异佛尔酮和异丙酮)三元体系的液-液平衡数据的实验测定和相关性

{水 + 1-丁醇 + 异佛尔酮} 和 {水 + 1-丁醇 + 异佛尔酮} 三元系统的液-液平衡 (LLE) 数据在大气压下的不同温度下进行了系统研究。应用 Othmer-Tobias 和 Bachman 方程来分析实验 LLE 数据的可靠性。选择性和分配系数用于评估萃取剂的萃取效率。应用非随机二液体 (NRTL) 和通用准化学 (UNIQUAC) 模型来关联所研究的系统,并且所有均方根偏差 (RMSD) 均小于 0.2%。同时,在关联过程中获得了这些化合物之间的二元相互作用参数。
更新日期:2020-01-01
down
wechat
bug