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Numerical Simulation of the Distribution Function and Free Energy of a Single Wormlike Polymer Confined between Hard Walls
Chinese Journal of Polymer Science ( IF 4.1 ) Pub Date : 2019-10-09 , DOI: 10.1007/s10118-019-2322-0
Yang Gu , Hui Zhang , Dong-Liang Zhang

We focus on the distribution and free energy of a wormlike polymer confined between two parallel hard walls. The variation in the distribution and free energy of the wormlike chain as the spacing between the walls decreases (or as the total contour length of the wormlike chain increases or as the persistence length of the chain increases) is simulated. The main reason for these changes is a degradation of the long wormlike chain into a Gaussian long chain under weak confinement.

中文翻译:

硬壁间单一蠕虫状聚合物的分布函数和自由能的数值模拟

我们专注于限制在两个平行的硬壁之间的蠕虫状聚合物的分布和自由能。随着壁间距的减小(或随着蠕虫链总轮廓长度的增加或链的持续长度的增加),蠕虫链的分布和自由能的变化得到了模拟。这些变化的主要原因是在弱约束下长蠕虫状链降解为高斯长链。
更新日期:2020-01-04
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