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Organo-f-Complexes for Efficient and Selective Hydroborations
Synthesis ( IF 2.2 ) Pub Date : 2020-01-02 , DOI: 10.1055/s-0039-1690762 Heng Liu 1, 2 , Moris S. Eisen 1
Synthesis ( IF 2.2 ) Pub Date : 2020-01-02 , DOI: 10.1055/s-0039-1690762 Heng Liu 1, 2 , Moris S. Eisen 1
Affiliation
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Organo-f-complexes catalyzing small molecule transformations have been a hot topic in the past few years. Compared to other transformations, the hydroboration of C=X (X = C, N, O) unsaturated bonds serves as an important strategy to prepare organoborane derivatives, which are important intermediates in organic synthesis. This review outlines recent advances in organolanthanide and organoactinide complexes promoting the hydroboration of C=X containing substrates. After a brief introduction, three types of hydroboration will be presented: alkene hydroboration, carbonyl hydroboration, and imine and nitrile hydroborations. The catalytic performance, mechanism, and kinetic studies are discussed in detail, aiming to emphasize the catalytic differences between the diverse organo-f-catalysts. Additionally, challenges and future directions of this field are also presented.
中文翻译：
高效选择性硼氢化的有机-f-络合物
在过去的几年中，催化小分子转化的有机f络合物一直是一个热门话题。与其他转化相比，C = X（X = C，N，O）不饱和键的硼氢化反应是制备有机硼烷衍生物的重要策略，有机硼烷衍生物是有机合成的重要中间体。这篇综述概述了有机镧系元素和有机act系元素络合物促进含C = X的底物进行硼氢化的最新进展。在简要介绍之后，将介绍三种类型的硼氢化：硼氢化硼，羰基硼氢化，亚胺和腈硼氢化。催化性能，机制和动力学研究进行了详细讨论，旨在强调不同的有机-之间的催化差异˚F-催化剂。此外，还提出了该领域的挑战和未来方向。
更新日期：2020-01-04
中文翻译：
高效选择性硼氢化的有机-f-络合物
在过去的几年中，催化小分子转化的有机f络合物一直是一个热门话题。与其他转化相比，C = X（X = C，N，O）不饱和键的硼氢化反应是制备有机硼烷衍生物的重要策略，有机硼烷衍生物是有机合成的重要中间体。这篇综述概述了有机镧系元素和有机act系元素络合物促进含C = X的底物进行硼氢化的最新进展。在简要介绍之后，将介绍三种类型的硼氢化：硼氢化硼，羰基硼氢化，亚胺和腈硼氢化。催化性能，机制和动力学研究进行了详细讨论，旨在强调不同的有机-之间的催化差异˚F-催化剂。此外，还提出了该领域的挑战和未来方向。
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