Visible-light-promoted acridine red catalyzed aerobic oxidative decarboxylative acylation of α-oxo-carboxylic acids with quinoxalin-2(1H)-ones,Organic Chemistry Frontiers

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Visible-light-promoted acridine red catalyzed aerobic oxidative decarboxylative acylation of α-oxo-carboxylic acids with quinoxalin-2(1H)-ones
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020/01/03 , DOI: 10.1039/c9qo01334b
Pengli Bao _{1,

2,

3,

4} , Fei Liu _{1,

2,

3,

4} , Yufen Lv _{1,

2,

3,

4} , Huilan Yue _{4,

5,

6,

7,

8} , Jiang-Sheng Li _{4,

9,

10,

11} , Wei Wei _{1,

2,

3,

4,

5}

Affiliation

A mild and facile visible-light-mediated strategy has been proposed for the synthesis of 3-acyl quinoxalin-2(1H)-ones through acridine red catalyzed aerobic oxidative decarboxylative acylation of α-oxo-carboxylic acids with quinoxalin-2(1H)-ones at room temperature in air. Various 3-acyl quinoxalin-2(1H)-ones could be efficiently obtained in good yields with excellent functional group compatibility.

中文翻译：

可见光促进的idine啶红催化喹喔啉-2（1H）-a对α-氧代羧酸的需氧氧化脱羧酰化反应

已经提出了一种温和且简便的可见光介导的策略，该方法通过through啶红催化α-氧代羧酸与喹喔啉-2（1）的需氧氧化脱羧酰化反应来合成3-酰基喹喔啉-2（1 H）- H）-室温下在空气中。可以以良好的产率和优异的官能团相容性有效地获得各种3-酰基喹喔啉-2（1 H）-one。

更新日期：2020-02-13

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