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Bending strain induced photocurrent crossover from positive to negative in the flexible organic phototransistors
Organic Electronics ( IF 2.7 ) Pub Date : 2020-01-03 , DOI: 10.1016/j.orgel.2019.105614
Huabiao Zhu , Yuhuan Yang , Yingquan Peng , Sunan Xu , Wenli Lv , Yi Wei , Lei Sun , Ying Wang

The understanding of bending strain effects on the performances of flexible organic phototransistors (FOPTs) is of great importance. In this manuscript, two kinds of FOPTs- single layer of copper phthalocyanine (CuPc) (SL-FOPTs) and hybrid planar bulk-heterojunction of CuPc/CuPc:PTCDA (HPBHJ-OPTs) with PTCDA denotes 3,4,9,10-perylenete-acarboxylic dianhydride, with polyvinyl alcohol as the gate dielectric but different active layer, were fabricated and their strain dependent performances investigated, respectively. For SL-FOPTs, at a given light intensity, with the bending-strain increasing, the photocurrent increases at first, and then decreases after reaching a maximum. A crossover from positive to negative occurs in this process, and the critical strain at which the crossover occurs increases with the illumination light intensity. Different from the observation in SL-FOPTs, the Idarkstrain curves in HPBHJ-FOPTs exhibit obtuse small peaks at low gate voltages of |Vg|≦10 V, and minimums at large gate voltages of |Vg|≧ 20 V. At large gate voltages with increasing bending strain, the photocurrent of HPBHJ-OPTs decreases and become negative (from positive) at first, with the decreasing rate nearly proportional to the gate voltage, and then increase after reaching a negative minimum. The physical origin of observed photocurrent crossover from positive to negative with increasing bending strain is discussed.



中文翻译:

弯曲应变引起的柔性有机光电晶体管中光电流从正向负转换

了解弯曲应变对柔性有机光电晶体管(FOPT)性能的影响非常重要。在本手稿中,两种FOPT:单层酞菁铜(CuPc)(SL-FOPT)和CuPc / CuPc:PTCDA(HPBHJ-OPTs)与PTCDA的混合平面体-异质结表示3,4,9,10-制备了以聚乙烯醇为栅极电介质但有源层不同的different-二羧酸二酐,并研究了其应变相关性能。对于SL-FOPT,在给定的光强度下,随着弯曲应变的增加,光电流首先增加,然后在达到最大值后减小。在此过程中发生从正到负的交叉,并且发生交叉的临界应变随着照明光强度而增加。应变在HPBHJ-FOPTs曲线在低栅极电压表现出钝角小峰| V g |≤10V,并且在大栅极电压为|时最小值 V g |≥20V。在较大的栅极电压下,随着弯曲应变的增加,HPBHJ-OPT的光电流首先下降,然后变为负值(从正值开始),下降率几乎与栅极电压成正比,然后在达到负的最小值。讨论了随着弯曲应变的增加,从正到负的光电流交叉的物理起源。

更新日期:2020-01-04
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