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Magnetic ordering of Sm26Co11Ga6-type R26Co9-6Ga8-11 compounds (R = Gd–Ho, Tm)
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2020-01-03 , DOI: 10.1016/j.jssc.2019.121162
A.V. Morozkin , A.V. Knotko , V.O. Yapaskurt , Jinlei Yao

The magnetic ordering of polycrystalline Sm26Co11Ga6-type {Gd, Dy, Ho, Tm}26Co9Ga8 and Tb26Co6-8Ga11-9 (space group P4/mbm, N 127, tP86) has been established using magnetic measurements. Gd26Co9Ga8 exhibits soft ferromagnetic with the Curie temperature of 124 K Tb26Co6Ga11, Tb26Co8Ga9, Dy26Co9Ga8 and Ho26Co9Ga8 show mixed ferro-antiferromagnic ordering with the Curie temperatures of 76 K, 74 K, 28 K and 16 K, respectively. They display permanent magnet properties at low temperatures. The novel Tm26Co9Ga8 demonstrates dominant antiferromagnetic ordering at 6 K, while it is a soft ferromagnet at 2 K.

Among these compounds, Tb26Co8Ga9 exhibits largest magnetocaloric effect with magnetic entropy change of −9.2 J/kg⋅K at 76–81 K and relative large cooling power of ∼560 J/kg (field change of 50 kOe), while Tb26Co6Ga11 is the best permanent magnet with a coercivity of 9 kOe, residual magnetization of 3.26 μB per Tb and theoretical energy product of 200 kJ/m3 at 2 K.



中文翻译:

Sm26Co11Ga6型R26Co9-6Ga8-11化合物的磁性排序(R = Gd–Ho,Tm)

多晶Sm 26 Co 11 Ga 6型{Gd,Dy,Ho,Tm} 26 Co 9 Ga 8和Tb 26 Co 6-8 Ga 11-9(空间群P 4 / mbm,N 127,tP 86)已使用磁测量建立。Gd 26 Co 9 Ga 8具有居里温度为124 K的软铁磁Tb 26 Co 6 Ga 11,Tb 26 Co 8 Ga 9,Dy26 Co 9 Ga 8和Ho 26 Co 9 Ga 8分别显示了居里温度分别为76 K,74 K,28 K和16 K的混合铁-反铁磁序列。它们在低温下表现出永磁特性。新型Tm 26 Co 9 Ga 8在6 K时表现出显着的反铁磁有序性,而在2 K时则是软铁磁体。

在这些化合物中,Tb 26 Co 8 Ga 9表现出最大的磁热效应,在76-81 K时的磁熵变为-9.2 J / kg·K,相对较大的冷却功率为560 J / kg(场变化为50 kOe),而Tb的26611为具有9千奥斯特,3.26μ的剩余磁化的矫顽力最好永久磁铁每Tb和理论能量乘积200千焦/平方米的3在2 K.

更新日期:2020-01-04
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