Two new two-dimensional, broadband, solid-state NMR experiments for separating and correlating the quadrupolar and shift interactions of spin $I=1$ nuclei in paramagnetic systems are proposed. The new pulse sequences incorporate the short, high-power adiabatic pulses (SHAPs) into the shifting d-echo experiment of Walder et al. [J. Chem. Phys., 142, 014201 (2015)], in two different ways, giving double and quadruple adiabatic shifting d-echo sequences. These new experiments have the advantage over previous methods of both suppressing spectral artefacts due to pulse imperfections, and exhibiting a broader excitation bandwidth. Both experiments are analysed with theoretical calculations and simulations, and are applied experimentally to the ²H NMR of deuterated CuCl₂ ⋅2H₂O, and two deuterated samples of the ion conductor oxyhydride BaTiO_3−xH_y prepared using two different methods. For the CuCl₂ ⋅2H₂O sample, both new methods obtain very high-quality spectra from which the parameters describing the shift and quadrupolar interaction tensors, and their relative orientation, were extracted. The two BaTiO_3−xH_y samples exhibited different local hydride environments with different tensor parameters. The ²H spectra of these oxyhydrides exhibit inhomogeneous broadening of the ²H shifts, and so whilst the quadrupolar interaction parameters were easily extracted, the measurement of the shift parameters was more complex. However, effective shift parameters were extracted, which combine the effects of both the paramagnetic shift tensor and the inhomogeneous broadening.

两个新的二维，宽带，固态NMR实验，用于分离和关联自旋的四极和位移相互作用 $\mathrm{一世}=\mathrm{1个}$提出了顺磁系统中的原子核。新的脉冲序列将短的高功率绝热脉冲（SHAP）整合到Walder等人的d d回波实验中。[J. 化学 Phys。，142，014201（2015）]，以两种不同方式给出了双重和四重绝热移位d回波序列。这些新的实验具有优于以前的方法的优点，既可以抑制由于脉冲缺陷引起的频谱伪影，又可以显示更宽的激励带宽。两个实验中，分析与理论计算和模拟，并且通过实验施加到²氘化的CuCl 1 H NMR ₂ ⋅2H ₂ O，和两个氘化oxyhydride的BaTiO离子导体样品_3-X ħ _ÿ使用两种不同的方法制备。为氯化亚铜₂ ⋅2H ₂ ö样品，这两种新的方法获得非常从该描述位移和四极相互作用张量，以及它们的相对取向的参数，提取高质量的光谱。两个BaTiO _{3− x} H _y样品表现出具有不同张量参数的不同局部氢化物环境。这些氢氧化物的² H光谱显示^2的不均匀加宽H位移，因此尽管很容易提取四极相互作用参数，但位移参数的测量更为复杂。然而，提取了有效的位移参数，其结合了顺磁位移张量和不均匀展宽的效果。