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Long-term performance of a UASB reactor treating acid mine drainage: effects of sulfate loading rate, hydraulic retention time, and COD/SO42- ratio.
Biodegradation ( IF 3.1 ) Pub Date : 2018-11-08 , DOI: 10.1007/s10532-018-9863-8
Mirabelle Perossi Cunha 1 , Rafael Marçal Ferraz 2 , Giselle Patrícia Sancinetti 2 , Renata Piacentini Rodriguez 2, 3
Affiliation  

Acid mine drainage (AMD) is among the most serious threats to water and the typical alkali-based treatment costs are high. This study’s main objective was the establishment of a highly efficient biological process using an upflow anaerobic sludge blanket (UASB) reactor to treat AMD based on a shorter hydraulic retention time (HRT) and lower organic matter input. The process was evaluated for a long-term operation (739 days) in terms of the influence of HRT (14–24 h), metal addition, sulfate loading rate (0.5–2.6 g SO42− l−1 d−1), and the COD/SO42− ratio (0.67–1.0) using ethanol as the only electron donor at a pH of 4.0. Neutral effluent pH was achieved throughout the time apart from operational modifications. The reduction in HRT from 24 to 16 h and an increase in the sulfate loading rate (SLR) up to 2.25 g SO42− l−1 d−1 improved the sulfate removal to (92.1 ± 1.8)% with 80% chemical oxygen demand (COD) removal. However, the sulfate reduction was less than 80% when the HRT and SLR was changed to 14 h and 2.6 g SO42− l−1 d−1, respectively. The oxidation of organic matter by sulfate reduction was greater than 50% regardless of the conditions imposed but the use of ethanol to treat AMD was more efficient when either the HRT was 16 h (1.5 g SO42− l−1 d−1) in the presence of Fe, Zn, and Cu or the HRT was 14 h (2.6 g SO42− l−1 d−1) but the COD/SO42− ratio was reduced to 0.67. The fully optimized conditions of the UASB reactor were set at an HRT of 16 h, SLR of 1.5 g SO42− l−1 d−1, and a COD/SO42− ratio of 1.0.

中文翻译:

UASB反应器处理酸性矿山排水的长期性能:硫酸盐上样速率,水力停留时间和COD / SO42-比率的影响。

酸性矿山排水(AMD)是对水的最严重威胁,典型的基于碱的处理成本很高。这项研究的主要目的是建立一个高效的生物工艺,该工艺使用上流厌氧污泥床(UASB)反应器,以较短的水力停留时间(HRT)和较低的有机质输入量为基础,处理AMD。根据HRT(14–24 h),金属添加,硫酸盐加载速率(0.5–2.6 g SO 4 2-  l -1  d -1)的影响,评估了该工艺的长期运行(739天)。,以及COD / SO 4 2−pH值为4.0时使用乙醇作为唯一的电子给体的比率(0.67–1.0)。除了进行操作修改外,在整个时间内均达到了中性废水的pH值。在HRT至16小时的还原从24和2.25克的增加硫酸盐加载速率(SLR)向上SO 4 2- 升-1  d -1提高硫酸盐除去至(92.1±1.8)%,用80%的化学氧去除需求(COD)。然而,硫酸盐还原是当HRT和SLR改变为14小时和2.6g小于80%SO 4 2- 升-1  d -1, 分别。的有机物由硫酸盐还原该氧化是不管所施加的条件大于50%,但使用乙醇来治疗AMD是更有效的时,无论是HRT为16小时(1.5克SO 4 2- 升-1  d -1)在铁,锌,和Cu或HRT的存在是14小时(2.6克SO 4 2- 升-1  d -1),但COD / SO 4 2-比降低到0.67。UASB反应器的完全优化的条件设定在16小时的HRT,1.5克SO SLR 4 2- 升-1  d -1,和COD / SO 4 2-比为1.0。
更新日期:2018-11-08
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