The properties of Eu-doped fluorochlorozirconate (FCZ) glass ceramics upon thermal processing and the influence of Eu-doping on the formation of BaCl(2) nanocrystals therein have been investigated. Differential scanning calorimetry indicates that higher Eu-doping shifts the crystallization peak of the nanocrystals in the glass to lower temperatures, while the glass transition temperature remains constant. The activation energy and the thermal stability parameters for the BaCl(2) crystallization are determined.

中文翻译：

---

掺铕氟锆酸盐基玻璃陶瓷的差示扫描量热法研究。

研究了 Eu 掺杂氟氯锆酸盐 (FCZ) 玻璃陶瓷在热处理过程中的性能以及 Eu 掺杂对其中形成的 BaCl(2) 纳米晶体的影响。差示扫描量热法表明，较高的 Eu 掺杂将玻璃中纳米晶体的结晶峰移至较低温度，而玻璃化转变温度保持不变。确定了 BaCl(2) 结晶的活化能和热稳定性参数。