A new 1-D coordination polymer {[Mn(6)O(2)(O(2)CMe)(10)(H(2)O)(4)].2.5H(2)O}(infinity) (1.2.5H(2)O)(infinity) and the cluster [Mn(6)O(2)(O(2)(O(2)CPh)(10) (py)(2)(MeCN)(H(2)O)].2MeCN (2.2MeCN) are reported. Both compounds were synthesized by room temperature reactions of [Mn(3)(mu(3)-O)(O(2)CR)(6)(L)(2)(L')] (R = Me, L = L' = py, (1.2.5H(2)O)(infinity); R = Ph, L = py, L' = H(2)O, 2.2MeCN) in the presence of 3-hydroxymethylpyridine (3hmpH) in acetonitrile. The structures of these complexes are based on hexanuclear mixed-valent manganese carboxylate clusters containing the [Mn(4) (II)Mn(2) (III)(mu(4)-O)(2)](10+) structural core. (1.2.5H(2)O)(infinity) consists of zigzag chain polymers constructed from [Mn(6)O(2)(O(2)CMe)(10)(H(2)O)(4)] repeating units linked through acetate ligands, whereas 2.2MeCN comprises a discrete Mn(6)-benzoate cluster.

中文翻译：

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基于 [Mn(6)(mu(4)-O)(2)] 单元的金属簇和配位聚合物的合成和结构表征。

一种新的一维配位聚合物 {[Mn(6)O(2)(O(2)CMe)(10)(H(2)O)(4)].2.5H(2)O}(infinity) ( 1.2.5H(2)O)(无穷大)和簇[Mn(6)O(2)(O(2)(O(2)CPh)(10) (py)(2)(MeCN)(H( 2)O)].2MeCN (2.2MeCN) 两种化合物均通过 [Mn(3)(mu(3)-O)(O(2)CR)(6)(L)( 2)(L')] (R = Me, L = L' = py, (1.2.5H(2)O)(infinity); R = Ph, L = py, L' = H(2)O, 2.2 MeCN) 在乙腈中 3-羟甲基吡啶 (3hmpH) 的存在下。这些配合物的结构基于含有 [Mn(4) (II)Mn(2) (III)(mu( 4)-O)(2)](10+) 结构核心。(1.2.5H(2)O)(infinity) 由由 [Mn(6)O(2)(O(2)CMe )(10)(H(2)O)(4)] 重复单元通过醋酸盐配体连接，而 2.2MeCN 包含一个离散的 Mn(6)-苯甲酸簇。