Introduction ................................................................................. 342 I. Recent Developments of Ullmann-type Reactions (C O, C N, C S)...................................................................................... 344 1. New Development of Ligands and Copper Complexes.............................344 a. C O Bond Formation .......................................................................344 b. C N Bond Formation........................................................................348 c. C S Bond Formation ........................................................................350 d. More Than One-Type Bond Formation ................................................351 2. Green Synthetic Methodology ...............................................................352 a. Ligandor Additive-free Conditions ....................................................352 b. Recyclable Heterogeneous Catalysts ...................................................356 c. Microwave/ultrasound-assisted Synthesis ............................................359 3. Mechanistic Study ................................................................................363 II. Recent Synthetic Applications in Heterocyclic, Medicinal, and Natural Products Chemistry................................................... 365 1. Heterocycles.........................................................................................365 a. C O Formation ................................................................................365 b. C N Formation ................................................................................368 c. C S Formation.................................................................................374 2. Medicinal Chemistry.............................................................................375 a. C O Formation ................................................................................375 b. C N Formation ................................................................................376 c. C S Formation.................................................................................379 3. Natural Products ..................................................................................379 a. C O Formation ................................................................................379 b. C N Formation ................................................................................382 Conclusion.................................................................................... 384 Acknowledgement......................................................................... 385 References .................................................................................... 385

中文翻译：

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乌尔曼反应的最新合成发展和应用。回顾

介绍 ................................................. ...................................... 342 I. 乌尔曼型反应（CO、CN、CS）的最新进展。 ………………………………………………………………………………………………………………………………………………………… ...................................................... 344 1. 配体与铜配合物的新发展...... ......................................344 a. CO 键的形成 ..................................... ......................................344 b. CN 债券的形成............................................................ ......................................348 c. CS 债券的形成 ..................................... ...................... 350 d. 不止一种类型的键形成 ..................................... .......351 2. 绿色合成方法...................................................... ......................................352 a. 配体无添加剂条件...... …………………………………………………………………………………………………………………………………………………………………………352 可回收的多相催化剂 ..................................................... ....356 摄氏度。微波/超声波辅助合成 ..................................... 359 3. 机理研究 ..................................... ......................................363 二. 最近在杂环、药物和天然产物化学中的合成应用...................................... ...................... 365 1. 杂环...................................... ………………………………………………………………………………………………………………………………………………………… ......365 CO 的形成 ..................................... …………………………………………………………………………………………………………………………………………………………………………………………365 CN 形成 ..................................... …………………………………………………………………………………………………………………………………………………………………………368 CS 编队............................................................ .................................................374 2. 药物化学 ........................................... ………………………………………………………………………………………………………………………………………………………… ………………375 CO 的形成 ..................................... …………………………………………………………………………………………………………………………………………………………………………………………………………375 CN 形成 ..................................... ……………………………………………………………………………………………………………………………………………………………………376 CS 编队............................................................ ......................................379 3. 天然产品 ..................... ………………………………………………………………………………………………………………………………………………………… ......................379 a. CO 的形成 ..................................... ……………………………………………………………………………………………………………………………………………………………………………………………………379 CN 形成 ..................................... ......................................382 结论...................... ………………………………………………………………………………………………………………………………………………………… ………………