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NHC-Based Self-Assembled Monolayers on Solid Gold Substrates.
Australian Journal of Chemistry ( IF 1.0 ) Pub Date : 2011-08-19 , DOI: 10.1071/ch11173
Tobias Weidner 1 , Joe E Baio , Alexander Mundstock , Christoph Große , Silvia Karthäuser , Clemens Bruhn , Ulrich Siemeling
Affiliation  

Thin films of 1,3-diethylbenzimidazol-2-ylidene (BIEt) were fabricated from THF solution on solid gold substrates and characterised by high-resolution X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopy. The surface-analytical data are in accord with the formation of self-assembled monolayers of BIEt molecules exhibiting an approximately vertical orientation on the substrate. The crystal structure of (BIEt)2 was also determined.



中文翻译:


固体金基底上基于 NHC 的自组装单层膜。



采用 THF 溶液在固体金基底上制备 1,3-二乙基苯并咪唑-2-亚基 (BIEt) 薄膜,并通过高分辨率 X 射线光电子和近边 X 射线吸收精细结构光谱进行表征。表面分析数据与 BIEt 分子自组装单层的形成一致,在基底上表现出近似垂直的方向。 (BIEt) 2的晶体结构也被确定。

更新日期:2011-08-19
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