We have calculated the electronic states of Rb(2) by multireference configuration interactions using the averaged relativistic effective small-core potential and the core-polarization potential. The potential energy curves for a large number of states dissociating into from 5s+5s up to 7s+5s asymptotic limits are calculated and the spectroscopic constants are reported. The spin-orbit effects for the states dissociating into 5p+5s and 4d+5s are calculated using the effective spin-orbit potential. The results are compared with available experimental data and other theoretical works. Copyright 2001 Academic Press.

中文翻译：

---

Rb2分子电子态的理论研究

我们已经使用平均相对论有效小核心电位和核心极化电位通过多参考配置相互作用计算了 Rb(2) 的电子状态。计算了从 5s+5s 到 7s+5s 渐近极限的大量状态的势能曲线，并报告了光谱常数。解离为 5p+5s 和 4d+5s 的状态的自旋轨道效应是使用有效自旋轨道势计算的。结果与可用的实验数据和其他理论工作进行了比较。版权所有 2001 学术出版社。