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A novel catalyst system for the synthesis of N,N′-Methylenebisacrylamide from acrylamide
Designed Monomers and Polymers ( IF 1.6 ) Pub Date : 2017-01-01 , DOI: 10.1080/15685551.2017.1332138
Abdullah Avşar 1 , Yener Gökbulut 1 , Burak Ay 1 , Selahattin Serin 1
Affiliation  

Abstract N,N′-Methylenebisacrylamide (MBAA), which is an important raw material in a widely industrial area, was synthesized using convenient catalysts. The synthesized monomer was fully characterized by the elemental analysis, fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), 1H-NMR, 13C-NMR, GC/MS, and high performance liquid chromatography (HPLC) analysis. Six different homogeneous and heterogeneous catalysts were used to obtain maximum monomer yield. The MBAA was obtained with 95% yield by using Cu(II) catalyst containing carboxylate groups ligands.

中文翻译:

一种用于从丙烯酰胺合成 N,N'-亚甲基双丙烯酰胺的新型催化剂体系

摘要 N,N'-亚甲基双丙烯酰胺(MBAA)是广泛工业领域的重要原料,采用简便的催化剂合成。通过元素分析、傅里叶变换红外 (FT-IR) 光谱、热重分析 (TGA)、1H-NMR、13C-NMR、GC/MS 和高效液相色谱 (HPLC) 分析对合成的单体进行了充分表征。使用六种不同的均相和非均相催化剂来获得最大单体产率。通过使用含有羧酸根基团配体的 Cu(II) 催化剂以 95% 的收率获得了MBAA。
更新日期:2017-01-01
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