An electrochemical cell coupled with a recycle loop through a transmission FTIR cell is employed in studies of two free radical organic reactions, the oxidation of allylic alcohols and the trifluoromethylation of heteroarenes. Rapid mixing through the recycle loop allows continuous monitoring of reaction progress. Electrochemical generation of free radicals allows their controlled mediation into the reaction mixture for more efficient reaction. Kinetic profiles provide mechanistic insight into reactions under electrochemical control.

中文翻译：

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循环反应器中电化学控制有机反应的原位 FTIR 光谱监测。

电化学电池通过透射 FTIR 电池与循环回路耦合，用于研究两种自由基有机反应：烯丙醇的氧化和杂芳烃的三氟甲基化。通过循环回路快速混合可以连续监测反应进度。自由基的电化学产生使其能够受控地介导到反应混合物中，从而实现更有效的反应。动力学曲线提供了电化学控制下反应的机制洞察。