张文雄2007年10月从日本理化学研究所回到北京大学化学与分子工程学院有机所工作，任副教授，在席振峰院士课题组开展科研工作，2016年晋升为教授，2017年获得国家杰出青年科学基金。通过国际评估等程序，2021年1月始，在北京大学化学与分子工程学院无机所建立“稀土金属有机化学”课题组，任课题组长/PI。本课题组围绕高活性稀土金属有机杂环化合物的合成、结构表征、成键模式及对小分子的活化和反应机理开展系列研究：首次实现了稀土金属杂环戊二烯的高效合成，在此基础上首次实现了从白磷出发直接构建有机膦化合物，为稀土金属及白磷的高效利用提供了新思路；首次实现了高张力稀土金属杂环丙烯的合成和结构表征，发现其具有休克尔芳香性；成功构建了双钐杂环戊烯，首次实现了双碳负离子型共轭烯烃的还原，揭示该双碳负离子的π反键轨道能够从能量更高的钐4f轨道接收两个电子。在已有工作基础上，拟开展：1）新的稀土金属有机杂环的合成，并研究与小分子，如白磷，CO，CO₂，氧气等的反应性和催化活性；探索芳香性稀土金属有机杂环的合成和成键模式；2）利用金属有机化学手段，建立简单、高效的白磷活化方法直接构建有机膦化合物，打破传统的工业路线，实现白磷的直接应用。

现课题组诚聘博士后研究人员数名，此招聘信息长期有效。要求在金属有机化学、或过渡金属配位化学、或元素有机化学、或光化学、或电化学研究领域有较好的工作积累，进站后开展稀土金属有机杂环化学或白磷的转化化学研究。

具体待遇等请联系：张文雄教授

https://www.chem.pku.edu.cn/ktz2/wjhxktzz/125454.htm

电话：010-62758294

电子信箱：wx_zhang@pku.edu.cn

代表性论文：

(*: Corresponding author, #: Authors contributed equally)

1.Yu Zheng,# Chang-Su Cao,# Wangyang Ma,# Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins, J. Am. Chem. Soc., 2020, 142, 10705-10714.

2.Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi, Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction, Chem. Soc. Rev., 2020, 49, 5810-5849.

3.Nan Li,# Botao Wu,# Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B₃N₃Ph₆) Dianion: Characterization and Two-Electron Reduction, Angew. Chem. Int. Ed., 2020, 59, 8868-8872.

4.Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi, Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity, J. Am. Chem. Soc., 2019, 141, 20547-20555.

5.Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation, J. Am. Chem. Soc., 2019, 141, 8773-8777.

6.Shanshan Du,# Jimin Yang,# Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds, J. Am. Chem. Soc., 2019, 141, 6843-6847.

7.Jianhao Yin,# Jiapeng Li,# Gao-Xiang Wang,# Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*, Dinitrogen Functionalization Affording Chromium Hydrazido Complex, J. Am. Chem. Soc., 2019, 141, 4241-4247.

8.Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang*, Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P₃ Complexes, Angew. Chem. Int. Ed., 2017, 56, 15886-15890.

9.Baosheng Wei, Liang Liu, Wen-Xiong Zhang*, and Zhenfeng Xi, Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca₄[O] Inverse Crown Ether Complex, Angew. Chem. Int. Ed., 2017, 56, 9188-9192.

10.Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi*, Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation, J. Am. Chem. Soc., 2017, 139, 13688-13691.

11.Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Spiro Metalla-aromatics of Pd, Pt, Rh: Synthesis and Characterization, J. Am. Chem. Soc., 2017, 139, 5039-5042.

12.Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes, Chem. Sci., 2017, 8, 6852-6856.

13.Wangyang Ma,# Chao Yu,# Tianyang Chen,# Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Metallacyclopentadienes: Synthesis, Structure and Reactivity, Chem. Soc. Rev., 2017, 46, 1160-1192.

14.Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts, Angew. Chem. Int. Ed., 2016, 55, 14762-14765.

15.Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Synthesis of Phospholyl Lithium from White Phosphorus, Angew. Chem. Int. Ed., 2016, 55, 9187-9190.

16.Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang*, and Zhenfeng Xi, Transition-Metal-Catalyzed Cleavage of C–N Single Bonds, Chem. Rev., 2015, 115, 12045-12090.

17.Yang Wang, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp³)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides, J. Am. Chem. Soc., 2012, 134, 2926-2929.

18.Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi*, Zirconocene and Si-Tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis, Acc. Chem. Res., 2011, 44, 541-551.

19.Yang Wang, Wen-Xiong Zhang*, Zitao Wang, and Zhenfeng Xi*, Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation, Angew. Chem. Int. Ed., 2011, 50, 8122-8126.

20.Zitao Wang, Yang Wang, Wen-Xiong Zhang*, Zhaomin Hou, and Zhenfeng Xi*, Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides, J. Am. Chem. Soc., 2009, 131, 15108-15109.