Oxidation of 4-tert-Butylcyclohexanol with Swimming Pool Bleach,Journal of Chemical Education

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Oxidation of 4-tert-Butylcyclohexanol with Swimming Pool Bleach
Journal of Chemical Education ( IF 2.5 ) Pub Date : 2018-12-06 00:00:00 , DOI: 10.1021/acs.jchemed.7b00809
Irene Dip ₁ , Christina Gethers ₁ , Tonya Rice ₁ , Thomas S. Straub ₁

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4-tert-Butylcyclohexanol is rapidly converted to 4-tert-butylcyclohexanone with swimming pool bleach in a homogeneous reaction at room temperature. This process introduces students to a heterocyclic compound not normally discussed in the introductory course and has significant advantages over standard procedures using swimming pool chlorine or household bleach. Secondary products are removed by filtration and extraction. Product purity can be determined by thin layer chromatography. Solvent evaporation provides a pure product in high yield that can be characterized by melting point, IR spectroscopy, and/or NMR spectroscopy.

中文翻译：

游泳池漂白剂对4-叔丁基环己醇的氧化

4-叔-Butylcyclohexanol迅速转化为4-叔游泳池漂白-butylcyclohexanone中在室温下均匀的反应。该方法向学生介绍了入门课程中通常不会讨论的杂环化合物，并且比使用泳池氯或家用漂白剂的标准程序具有明显优势。通过过滤和萃取除去副产物。产物纯度可以通过薄层色谱法确定。溶剂蒸发提供了高产率的纯产物，其可以通过熔点，IR光谱和/或NMR光谱表征。

更新日期：2018-12-06

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