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Effect of nonionic surfactant as an electrolyte additive on the performance of aluminum-air battery
Journal of Power Sources ( IF 8.1 ) Pub Date : 2018-12-03 , DOI: 10.1016/j.jpowsour.2018.11.086
M.A. Deyab

In this work, the aluminum-air battery performance is improved by adding nonionic surfactant (nonoxynol-9) to battery electrolyte (4.0 M NaOH). The efficiency of nonoxynol-9 is determined using hydrogen gas evolution and electrochemical measurements. The surface analysis is explored using scan electron microscope and energy dispersive X-ray spectroscopy. Battery performance is investigated at 20 mA cm−2. The results show that the battery performance is significantly improved by adding nonoxynol-9. This is due to the low corrosion rate of aluminum in 4.0 NaOH solution resulted from physical adsorption of nonoxynol-9 on aluminum surface. The surfactant suppresses the hydrogen gas evolution and increases the anode utilization and capacity density. The maximum inhibition efficiencies of nonoxynol-9 from hydrogen gas evolution and electrochemical measurements are 85.6% and 92.8%, respectively at 2.0 mM. Nonoxynol-9 behaves as a cathodic-type inhibitor and its adsorption complies with Freundlich type isotherm. The adsorption of surfactant on the aluminum surface is emphasized by surface analysis.



中文翻译:

非离子表面活性剂作为电解质添加剂对铝空气电池性能的影响

在这项工作中,通过向电池电解质(4.0 M NaOH)中添加非离子表面活性剂(nonoxynol-9)来改善铝空气电池的性能。使用氢气放出和电化学测量来确定Nonoxynol-9的效率。使用扫描电子显微镜和能量色散X射线光谱仪探索表面分析。在20 mA cm -2的条件下研究电池性能。结果表明,通过添加壬诺酚9可以显着提高电池性能。这是由于壬醇9在铝表面上的物理吸附所致,铝在4.0 NaOH溶液中的腐蚀速率较低。表面活性剂抑制氢气逸出并增加阳极利用率和容量密度。从氢气放出和电化学测量得出的壬诺酚9的最大抑制效率在2.0 mM时分别为85.6%和92.8%。Nonoxynol-9表现为阴极型抑制剂,其吸附符合Freundlich型等温线。表面分析强调了表面活性剂在铝表面的吸附。

更新日期:2018-12-03
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