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Interactions, joining and microstructure of Sn-Ti/ZrO2 system
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2018-12-03 , DOI: 10.1016/j.jeurceramsoc.2018.12.010
Wei Fu , Xiaoguo Song , Alberto Passerone , Shengpeng Hu , Hong Bian , Yixuan Zhao , Meirong Wang , Fabrizio Valenza

Brazing and soldering following pre-metallization were employed to obtain reliable ZrO2/Sn-Ti/ZrO2 joints. Both the metallization and brazing depend on the wettability of ZrO2 by Sn-Ti alloys. The interfacial microstructure of joints was analyzed by SEM, XRD and TEM, and the shear strength of joints was evaluated. Good brazed joints and fully covered metallization layers, leading to good soldered joints, were obtained by the Sn-4Ti and Sn-8Ti alloys, while unsatisfactory results were obtained with Sn-1Ti and Sn-2Ti alloys owing to their limited wettability on ZrO2. Both kinds of ZrO2/Sn-Ti/ZrO2 joints possessed a β-Sn matrix with Ti6Sn5 and Ti2O3 interfacial layers. A higher Ti concentration per unit area induced the formation of a Ti11.31Sn3O10 layer along with the reduction of the Ti2O3 layer thickness at the interface in the soldered joints. All the joints exhibited a similar shear strength of 22 ~ 28 MPa and fractured through the β-Sn matrix.



中文翻译:

Sn-Ti / ZrO 2系统的相互作用,结合和微观结构

在预金属化之后进行钎焊和软焊以获得可靠的ZrO 2 / Sn-Ti / ZrO 2接头。金属化和钎焊均取决于Sn-Ti合金对ZrO 2的润湿性。通过SEM,XRD和TEM分析了接头的界面微观结构,并评估了接头的剪切强度。Sn-4Ti和Sn-8Ti合金获得了良好的钎焊接头和充分覆盖的金属化层,从而导致了良好的钎焊接头,而Sn-1Ti和Sn-2Ti合金由于在ZrO 2上的润湿性有限而获得的结果并不令人满意。。两种ZrO 2 / Sn-Ti / ZrO 2接头均具有带有Ti 6 Sn 5的β-Sn基体Ti 2 O 3界面层。单位面积中较高的Ti浓度会导致形成Ti 11.31 Sn 3 O 10层,并且会降低焊接接头界面处的Ti 2 O 3层厚度。所有接头均表现出相似的抗剪强度,为22〜28 MPa,并通过β-Sn基体断裂。

更新日期:2018-12-03
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