B₂O₃-containing MgO-Al₂O₃-SiO₂-Li₂O glass-ceramics were fabricated via crystallization treatment of primal glasses for the purpose of joining Si₃N₄ ceramics. The effects of B₂O₃ content on the crystallization behavior, coefficient of thermal expansion and softening temperature of MgO-Al₂O₃-SiO₂-Li₂O-B₂O₃ glasses were investigated. The results reveal that the glass transition temperature and the crystallization temperature of the glasses decrease with the increasing B₂O₃ content. It also demonstrates that γ-spodumene solid solution is detected in the glass-ceramics after heat treatment at 735 °C and 840 °C, respectively, whereas the heat treatment at 1000 °C results in the precipitation of β/γ-spodumene coexisting phases solid solution and forsterite. Additionally, by controlling the composition and crystallization treatment, the CTEs of glass-ceramics can be matched with the Si₃N₄. Furthermore, contact angle measurement confirms that the glass-ceramics possess a good wettability on the Si₃N₄ substrate, which can be considered as the candidate materials for joining Si₃N₄ ceramics.

为了接合Si ₃ N ₄陶瓷，通过对原玻璃进行结晶处理，制造了含有B ₂ O ₃的MgO-Al ₂ O ₃ -SiO ₂ -Li ₂ O玻璃陶瓷。B ₂ O ₃含量对MgO-Al ₂ O ₃ -SiO ₂ -Li ₂ O-B ₂ O ₃的结晶行为，热膨胀系数和软化温度的影响眼镜进行了调查。结果表明，玻璃的转变温度和结晶温度随着B ₂ O ₃含量的增加而降低。这也表明在分别于735°C和840°C的热处理后在玻璃陶瓷中检测到γ-锂辉石固溶体，而在1000°C的热处理导致β/γ-锂辉石共存相的析出固溶体和镁橄榄石。另外，通过控制组成和结晶处理，可以使玻璃陶瓷的CTE与Si ₃ N ₄匹配。此外，接触角测量证实了玻璃陶瓷在Si ₃ N ₄上具有良好的润湿性。基板，可以考虑用作连接Si ₃ N ₄陶瓷的候选材料。