Continuous flow aerobic alcohol oxidation using a heterogeneous Ru0 catalyst†,Reaction Chemistry & Engineering

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Continuous flow aerobic alcohol oxidation using a heterogeneous Ru0 catalyst†
Reaction Chemistry & Engineering ( IF 3.4 ) Pub Date : 2018-11-30 00:00:00 , DOI: 10.1039/c8re00212f
Julien Sofack Kreutzer _{1,

2,

3,

4,

5} , Laurent Vanoye _{1,

2,

3,

4,

5} , Boris Guicheret _{1,

2,

3,

4,

5} , Régis Philippe _{1,

2,

3,

4,

5} , Estelle Metay _{1,

4,

5,

6,

7} , Marie-Christine Duclos _{1,

4,

5,

6,

7} , Marc Lemaire _{1,

4,

5,

6,

7} , Claude De Bellefon _{1,

2,

3,

4,

5} , Pascal Fongarland _{1,

2,

3,

4,

5} , Alain Favre-Réguillon _{1,

2,

3,

4,

5}

Affiliation

The continuous selective aerobic oxidation of benzyl alcohol in flow was developed using an immobilized Ru⁰ catalyst. After optimization of the reaction conditions, the stability and productivity of the equipment were examined over time using tert-amyl alcohol as solvent, and no deactivation occurred. A cumulative TON close to 15 000 was obtained with a constant activity (TOF = 4 min⁻¹). A semi-empirical kinetic rate expression was proposed.

中文翻译：

使用非均相Ru ⁰催化剂进行的连续流好氧醇氧化†

使用固定化的Ru ⁰催化剂，对流动中的苯甲醇进行了连续的选择性好氧氧化。在优化反应条件之后，使用叔戊醇作为溶剂随时间检查设备的稳定性和生产率，并且没有发生失活。以恒定的活性（TOF = 4 min ^-1）获得了接近15000的累积TON 。提出了半经验动力学速率表达式。

更新日期：2018-11-30

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