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Dielectric characterization of a novel Bi2O3-Nb2O5-SiO2-Al2O3 glass-ceramic with excellent charge-discharge properties
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2018-11-27 , DOI: 10.1016/j.jeurceramsoc.2018.11.040
Jia Tian , Shujian Wang , Tao Jiang , Kaikai Chen , Jiwei Zhai , Bo Shen

A newly designed glass-ceramic system consisting of 15Bi2O3-15Nb2O5-40SiO2-30Al2O3 was successfully prepared, which was followed by its controlled crystallization at different heating temperatures. The effects of crystallization temperature on the microstructure, phase evolution and the energy storage behaviors of the novel material were systematically investigated. A maximum theoretical energy storage density of up to 15.3 J/cm3 was found in the samples heated at 800 °C. The polarization-electric (PE) hysteresis loops of this material exhibited very good linear character and high energy efficiency. In addition, an approximate value of 25 ns for discharged period T has been obtained, which demonstrated that most of the energy stored in dielectric was released over a very short time. The maximum powder density exceeds a high value of 90 MW/cc in a 390 kV/cm electric field. Therefore, the new developed Bi2O3-Nb2O5-SiO2-Al2O3 glass-ceramic can be used as an alternative, promising high-performance electrostatic capacitor material.



中文翻译:

具有优异的充放电性能的新型Bi 2 O 3 -Nb 2 O 5 -SiO 2 -Al 2 O 3微晶玻璃的介电特性

成功制备了由15Bi 2 O 3 -15Nb 2 O 5 -40SiO 2 -30Al 2 O 3组成的新设计的玻璃-陶瓷体系,随后在不同的加热温度下进行了可控的结晶。系统地研究了结晶温度对新型材料的微观结构,相演化和储能性能的影响。最大理论储能密度高达15.3 J / cm 3在加热到800°C的样品中发现了。这种材料的极化电(PE)磁滞回线表现出非常好的线性特性和高能效。另外,对于放电周期T,获得了大约25 ns的值,这表明存储在电介质中的大部分能量是在很短的时间内释放的。在390 kV / cm的电场中,最大粉末密度超过90 MW / cc的高值。因此,可以将新开发的Bi 2 O 3 -Nb 2 O 5 -SiO 2 -Al 2 O 3玻璃陶瓷用作替代品,有望成为高性能的静电电容材料。

更新日期:2018-11-27
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