Cover Feature: Hydrogen‐Bonding‐Assisted Supramolecular Metal Catalysis (Chem. Asian J. 23/2018),Chemistry - An Asian Journal

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Cover Feature: Hydrogen‐Bonding‐Assisted Supramolecular Metal Catalysis (Chem. Asian J. 23/2018)
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2018-11-27 , DOI: 10.1002/asia.201801480
Nilesh R. Mote _{1,

2} , Samir H. Chikkali _{1,

2}

Affiliation

Supramolecular chemistry requires multiple weak interactions to deliver self‐assembled catalysts with diverse structures, and orients substrates to achieve high activity and exceptional selectivity (as shown in the picture). Applications of hydrogen bonding as a construction element and as a directing group in recent supramolecular metal catalysis is presented. The concept has been successfully utilized in hydrogenation, hydroformylation, hydrocyanation, hydration, nitro‐aldol, epoxidation, and polymerization reactions, as well as C−H activation. Some of these reactions qualify for industrial applications. More information can be found in the Focus Review by Nilesh R. Mote and Samir H. Chikkali on page 3623 in Issue 23, 2018 (DOI: 10.1002/asia.201801302).

中文翻译：

封面功能：氢键辅助超分子金属催化（Chem.Asian J.23 / 2018）

超分子化学需要多重弱相互作用才能提供具有不同结构的自组装催化剂，并使基质取向以实现高活性和出色的选择性（如图所示）。提出了氢键作为一种构造元素和作为一个指导基团在最近的超分子金属催化中的应用。该概念已成功用于氢化，加氢甲酰化，氢氰化，水合，硝基羟醛，环氧化和聚合反应以及CH活化。这些反应中的一些符合工业应用的条件。有关更多信息，请参见Nilesh R.Mote和Samir H.Chikkali在2018年第23期第3623页上的焦点评论（DOI：10.1002 / asia.201801302）。

更新日期：2018-11-27

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