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Plasticizer incorporated, novel eco-friendly bio-polymer based solid bio-membrane for electrochemical clean energy applications
Polymer Degradation and Stability ( IF 6.3 ) Pub Date : 2018-11-15 , DOI: 10.1016/j.polymdegradstab.2018.11.013
P. Perumal , P. Christopher Selvin , S. Selvasekarapandian , P. Sivaraj , K.P. Abhilash , V. Moniha , R. Manjula Devi

High-molecular-weight, carbohydrate based Solid Biopolymer Electrolyte (SBE) pectin-lithium perchlorate [C6H10O7:LiClO4 = 60:40 molar mass percentage (m.m.%)] with ethylene carbonate (EC) as plasticizer has been prepared by simple solution casting technique. Addition of EC results in enhanced electrochemical window from 3.39 V to 3.55 V. The flexibility of the SBE is also improved which leads to attain an enriched ionic conductivity of 3.89 × 10−4 Scm−1 in the sample with optimum salt and plasticizer composition. The eco-friendly membrane with highest conductivity contributes good cycling properties and possesses higher value of cationic transference number when compared with other electrolyte samples. A lithium ion conducting battery constructed using the highly conducting polymer membrane sample is used to light up the red LED, display an Open Circuit Voltage (OCV) of 1.65 V.



中文翻译:

包含增塑剂,基于新型生态友好型生物聚合物的固体生物膜,用于电化学清洁能源应用

高分子量,基于碳水化合物的固体生物聚合物电解质(SBE)果胶-高氯酸锂[C 6 H 10 O 7:LiClO 4  = 60:40摩尔质量百分比(mm%)]已经使用碳酸亚乙酯(EC)作为增塑剂。通过简单的溶液浇铸技术制备。添加EC可使电化学窗口从3.39 V提高到3.55V。SBE的柔韧性也得到了改善,从而获得了3.89×10 -4 Scm -1的富离子电导率。在样品中具有最佳的盐和增塑剂组成。与其他电解质样品相比,具有最高电导率的环保膜具有良好的循环性能,并具有更高的阳离子转移数值。使用高导电聚合物膜样品构建的锂离子导电电池用于点亮红色LED,显示1.65 V的开路电压(OCV)。

更新日期:2018-11-15
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