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Cobalt‐Catalyzed Reductive Alkylation of Amines with Carboxylic Acids
ChemSusChem ( IF 7.5 ) Pub Date : 2018-11-29 , DOI: 10.1002/cssc.201802144
Balakumar Emayavaramban 1 , Priyanka Chakraborty 1 , Basker Sundararaju 1
Affiliation  

Direct reductive alkylation of amines with carboxylic acid is carried out by using an inexpensive, air‐stable cobalt/triphos catalytic system with molecular hydrogen as the reductant. This efficient synthetic method proceeds through reduction and condensation, followed by reduction of the in situ‐generated imine into the amine in a green catalytic process.

中文翻译:

钴催化的羧酸与胺的还原烷基化

胺与羧酸的直接还原烷基化反应是通过使用廉价的,空气稳定的钴/三磷催化体系(分子氢为还原剂)进行的。这种有效的合成方法是通过还原和缩合进行的,然后在绿色催化过程中将原位生成的亚胺还原为胺。
更新日期:2018-11-29
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