Cobalt‐Catalyzed Reductive Alkylation of Amines with Carboxylic Acids,ChemSusChem

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Cobalt‐Catalyzed Reductive Alkylation of Amines with Carboxylic Acids
ChemSusChem ( IF 7.5 ) Pub Date : 2018-11-29 , DOI: 10.1002/cssc.201802144
Balakumar Emayavaramban ₁ , Priyanka Chakraborty ₁ , Basker Sundararaju ₁

Affiliation

Direct reductive alkylation of amines with carboxylic acid is carried out by using an inexpensive, air‐stable cobalt/triphos catalytic system with molecular hydrogen as the reductant. This efficient synthetic method proceeds through reduction and condensation, followed by reduction of the in situ‐generated imine into the amine in a green catalytic process.

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